Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate
文献类型：期刊论文
| 作者 | Chen, Juanjuan1,2; Wang, Chang2; Dong, Bin2; Leng, Wenguang2; Huang, Jun1; Ge, Rile2; Gao, Yanan2 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 36期号:3页码:336-343 |
| 关键词 | Glycerol carbonate Glycerol Urea Ionic liquid |
| 英文摘要 | acidic, basic and neutral ionic liquids (ils) have been used as catalysts in the carbonylation of glycerol with urea. the results show that neutral ils have high catalytic activity in the reaction. the excellent performance of the catalysts can be attributed to the synergistic effect of the cation and anion. we speculated that the cation with positive charge activates urea, and the anion with negative charge activates glycerol. in addition, the well balanced acid-basic properties of the catalysts are necessary for good catalytic performance. the ils can be reused at least five times without loss of activity. using ils, instead of the traditional metal catalysts, reduces the use of non-renewable resources. it is eco-friendly that two inexpensive and bio-based raw materials were used and the catalytic reaction was carried out without solvent. (c) 2015, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | allyl glycidyl ether ; cyclic carbonates ; metal-oxides ; efficient ; acid ; hydrogen ; dioxide ; electrochemistry ; carbonylation ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351029200011 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146091]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanjing Tech Univ, Coll Chem & Chem Engn, Nanjing 210009, Jiangsu, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Juanjuan,Wang, Chang,Dong, Bin,et al. Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate[J]. chinese journal of catalysis,2015,36(3):336-343. |
| APA | Chen, Juanjuan.,Wang, Chang.,Dong, Bin.,Leng, Wenguang.,Huang, Jun.,...&Gao, Yanan.(2015).Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate.chinese journal of catalysis,36(3),336-343. |
| MLA | Chen, Juanjuan,et al."Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate".chinese journal of catalysis 36.3(2015):336-343. |
入库方式： OAI收割
来源：大连化学物理研究所
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