The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)
文献类型：期刊论文
| 作者 | Pan, Lu1; Gao, Xiao-Han1; Lv, Xue-Chuan1; Cao, Hui1; Tan, Zhi-Cheng2; Jiao, Yu-Juan1; Geng, Ren-Yong1; Luo, Guan-Hua1 |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 68期号:5页码:823-834 |
| 关键词 | Rare earth Complexes Cluster Structure Fluorescence |
| 英文摘要 | two heptanuclear trigonal prismatic polyhedra, [eucu6(-oh)(3)(gly)(6)im(6)](clo4)(6)3h(2)o and [smcu6(-oh)(3)(gly)(6)im(6)](clo4)(6)3h(2)o were synthesized through self-assembly of eu3+(sm3+), cu2+, glycine, and imidazole in aqueous solution and characterized by x-ray single crystal diffraction. both complexes crystallize in the rhombohedral r3 space group (a=b=15.8673 angstrom, c=23.4038 angstrom, v=5103.0(6)angstrom(3), z=3) and (a=b=15.8749 angstrom, c=23.455 angstrom, v=5119.1(8)angstrom(3), z=3). in the clusters, sm3+ and eu3+ ions are situated in the center of a prism formed by six copper ions and coordinate to nine oxygens with a tricapped trigonal prismatic coordination polyhedron. six glycinato ligands and six imidazole terminal ligands (each coordinates to one cu2+) construct the cluster. the fluorescent excitation and emission spectra showed that the complexes have strong ligand-based fluorescence. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | crystal-structures ; molecular-structure ; magnetic-properties ; metal-complexes ; imidazole ; ligands ; copper(ii) ; polymers ; series ; anion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350968600007 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146097]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Coll Chem Engn & Environm, Fushun, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Lu,Gao, Xiao-Han,Lv, Xue-Chuan,et al. The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)[J]. journal of coordination chemistry,2015,68(5):823-834. |
| APA | Pan, Lu.,Gao, Xiao-Han.,Lv, Xue-Chuan.,Cao, Hui.,Tan, Zhi-Cheng.,...&Luo, Guan-Hua.(2015).The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm).journal of coordination chemistry,68(5),823-834. |
| MLA | Pan, Lu,et al."The synthesis, structure, and fluorescence properties of two heptanuclear coordination compounds containing trigonal prismatic [LnCu(6)(mu-OH)(3)(Gly)(6)Im(6)](6+) cations (Ln: Eu, Sm)".journal of coordination chemistry 68.5(2015):823-834. |
入库方式： OAI收割
来源：大连化学物理研究所
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