Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose
文献类型：期刊论文
| 作者 | Sheng, Xueru1,2; Li, Ning1; Li, Guangyi1; Wang, Wentao1; Yang, Jinfan1,2; Cong, Yu1; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | scientific reports
 |
| 出版日期 | 2015-03-31 |
| 卷号 | 5 |
| 英文摘要 | for the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (hdo). the solvent-free guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and raney metals. among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (mgal-ht) and raney ni (or raney co) exhibited the best performances. over them, high carbon yield (96.7%) of c-10 and c-15 oxygenates was achieved. the guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of ni catalysts. these alkanes have high densities (0.86 g ml(-1) and 0.91 g ml(-1)) and can be used as high density aviation fuels or additives to bio-jet fuel. among the investigated hdo catalysts, the 35 wt.% ni-sio2-dp prepared by deposition-precipitation method exhibited the highest activity. |
| WOS标题词 | science & technology |
| 类目[WOS] | multidisciplinary sciences |
| 研究领域[WOS] | science & technology - other topics |
| 关键词[WOS] | high-quality diesel ; pot catalytic conversion ; renewable diesel ; transportation fuels ; liquid alkanes ; range alkanes ; bio-oil ; biomass ; hemicellulose ; hydrodeoxygenation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351947900001 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146121]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sheng, Xueru,Li, Ning,Li, Guangyi,et al. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose[J]. scientific reports,2015,5. |
| APA | Sheng, Xueru.,Li, Ning.,Li, Guangyi.,Wang, Wentao.,Yang, Jinfan.,...&Zhang, Tao.(2015).Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose.scientific reports,5. |
| MLA | Sheng, Xueru,et al."Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose".scientific reports 5(2015). |
入库方式： OAI收割
来源：大连化学物理研究所
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