Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds
文献类型：期刊论文
| 作者 | Hu, Xin-Hu; Liu, Zhen-Ting; Shao, Long; Hu, Xiang-Ping |
| 刊名 | synthesis-stuttgart
 |
| 出版日期 | 2015-04-01 |
| 卷号 | 47期号:7页码:913-923 |
| 关键词 | cycloaddition asymmetric catalysis propargylic compound ruthenium copper palladium gold |
| 英文摘要 | terminal propargylic compounds containing an alkyne unit and an alcohol or ester group in the propargylic position have a fairly acidic acetylenic hydrogen atom; this makes them versatile substrates for further chemical transformation. some transition metals such as ruthenium or copper exhibit specific affinity for terminal propargylic compounds, generating dielectrophilic ruthenium- or copper-allenylidene complexes that show high potential for stereoselective cycloaddition with various bis-nucleophiles. in this review, we highlight this emerging field of catalytic stereoselective cycloaddition with terminal propargylic compounds. examples of ruthenium-, copper-, palladium-, and gold-catalyzed cycloaddition are given in the article, along with mechanistic considerations. 1 introduction 2 ruthenium-allenylidene complexes in enantioselective cycloaddition 3 copper-allenylidene complexes in enantioselective cycloaddition 4 palladium-propargyl complexes in stereoselective cycloaddition 5 gold-carbenoid complexes in stereoselective cycloaddition 6 summary and outlook |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | sesquiterpene hydroquinone derivatives ; functionally-substituted aryl ; enantioselective synthesis ; 1,3-dicarbonyl compounds ; allenylidene complexes ; carbon nucleophiles ; beta-ketoesters ; amination ; esters ; acetates |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351584500002 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146122]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Xin-Hu,Liu, Zhen-Ting,Shao, Long,et al. Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds[J]. synthesis-stuttgart,2015,47(7):913-923. |
| APA | Hu, Xin-Hu,Liu, Zhen-Ting,Shao, Long,&Hu, Xiang-Ping.(2015).Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds.synthesis-stuttgart,47(7),913-923. |
| MLA | Hu, Xin-Hu,et al."Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds".synthesis-stuttgart 47.7(2015):913-923. |
入库方式： OAI收割
来源：大连化学物理研究所
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