Highly Effective Configurational Assignment Using Bisthioureas as Chiral Solvating Agents in the Presence of DABCO
文献类型：期刊论文
| 作者 | Bian, Guangling1; Fan, Hongjun2; Huang, Huayin1; Yang, Shiwei1; Zong, Hua1; Song, Ling1; Yang, Genjin3 |
| 刊名 | organic letters
 |
| 出版日期 | 2015-03-20 |
| 卷号 | 17期号:6页码:1369-1372 |
| 英文摘要 | a highly effective h-1 nmr method for determining the absolute configurations of various chiral a-hydroxyl acids and their derivatives has been developed with the use of bisthioureas (r)-csa 1 and (s)-csa 1 as chiral solvating agents in the presence of dabco, giving distinguishable proton signals with up to 0.66 ppm chemical shift nonequivalence. computational modeling studies were performed with gaussian09 to reveal the chiral recognition mechanism. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | absolute-configuration ; carboxylic-acids ; hydroxy-acids ; nmr ; alcohols ; cyanohydrins |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351558100006 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146127]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 3.Second Mil Med Univ, Sch Pharm, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bian, Guangling,Fan, Hongjun,Huang, Huayin,et al. Highly Effective Configurational Assignment Using Bisthioureas as Chiral Solvating Agents in the Presence of DABCO[J]. organic letters,2015,17(6):1369-1372. |
| APA | Bian, Guangling.,Fan, Hongjun.,Huang, Huayin.,Yang, Shiwei.,Zong, Hua.,...&Yang, Genjin.(2015).Highly Effective Configurational Assignment Using Bisthioureas as Chiral Solvating Agents in the Presence of DABCO.organic letters,17(6),1369-1372. |
| MLA | Bian, Guangling,et al."Highly Effective Configurational Assignment Using Bisthioureas as Chiral Solvating Agents in the Presence of DABCO".organic letters 17.6(2015):1369-1372. |
入库方式： OAI收割
来源：大连化学物理研究所
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