One-Pot Catalytic Transformation of Dicyclopentadiene to High Energy Density Fuel Exo-tetrahydrotricyclopentadiene
文献类型：期刊论文
| 作者 | Wang, Wentao; Cong, Yu; Chen, Shuai; Sun, Caixia; Wang, Xiaodong; Zhang, Tao |
| 刊名 | topics in catalysis
 |
| 出版日期 | 2015-04-01 |
| 卷号 | 58期号:4-6页码:350-358 |
| 关键词 | High energy density fuel Tricyclopentadiene Hydrogenation Isomerization Exo-tetrahydrotricyclopentadiene |
| 英文摘要 | energy density of fuel is an important issue for advanced aircrafts and spacecrafts. exo-tetrahydrotricyclopentadiene (exo-thtcpd) is a promising high-energy density fuel candidate with many desirable properties, including high volumetric energy content (43.2 mj/l), high density (1.04 g/ml) and low freezing point (<-40 a degrees c). in this work, we demonstrated the first example of one-pot catalytic synthesis of exo-thtcpd directly from dicyclopentadiene (dcpd). the whole procedure was fulfilled in one-pot by three steps. first, tricyclopentadiene (tcpd) was prepared directly from the dissociation-recombination of dcpd at 200 a degrees c. then the reaction mixture (the majority is tcpd, mixed with small amount of dcpd and tetracyclopentadiene) was saturated using supported noble metal catalysts at 150 a degrees c under 4.0 mpa h-2. finally, the hydrogenated mixture was treated by alcl3-catalytic isomerization at 15 a degrees c. like most synthesis processes, fractional distillation was needed to obtain the final product of exo-thtcpd. compared with previous routes, the new protocol has many advantages such as one-pot, high concentration, less solvents, low catalyst loading, short reaction time, etc, and therefore showed great potential for industrial applications. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | pd-b/gamma-al2o3 amorphous catalyst ; liquid-phase ; hydrogenation ; tricyclopentadiene ; isomerization ; tetrahydrodicyclopentadiene ; cyclopentadiene ; step |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351668200018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146134]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wentao,Cong, Yu,Chen, Shuai,et al. One-Pot Catalytic Transformation of Dicyclopentadiene to High Energy Density Fuel Exo-tetrahydrotricyclopentadiene[J]. topics in catalysis,2015,58(4-6):350-358. |
| APA | Wang, Wentao,Cong, Yu,Chen, Shuai,Sun, Caixia,Wang, Xiaodong,&Zhang, Tao.(2015).One-Pot Catalytic Transformation of Dicyclopentadiene to High Energy Density Fuel Exo-tetrahydrotricyclopentadiene.topics in catalysis,58(4-6),350-358. |
| MLA | Wang, Wentao,et al."One-Pot Catalytic Transformation of Dicyclopentadiene to High Energy Density Fuel Exo-tetrahydrotricyclopentadiene".topics in catalysis 58.4-6(2015):350-358. |
入库方式： OAI收割
来源：大连化学物理研究所
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