Synthesis of Lignin-Derived Bisphenols Catalyzed by Lignosulfonic Acid in Water for Polycarbonate Synthesis
文献类型：期刊论文
| 作者 | Chen, Qin1,2; Huang, Wei3; Chen, Peng3; Peng, Chang1; Xie, Haibo1; Zhao, Zongbao Kent1; Sohail, Muhammad1; Bao, Ming2 |
| 刊名 | chemcatchem
 |
| 出版日期 | 2015-04-01 |
| 卷号 | 7期号:7页码:1083-1089 |
| 关键词 | biomass green chemistry lignin-derived bisphenol sustainable chemistry water chemistry |
| 英文摘要 | lignosulfonic acid, a byproduct of the paper industry, was demonstrated to be an efficient and green catalyst in water for the stoichiometric condensation of creosol with formaldehyde to synthesize lignin-derived renewable bisphenols. the distribution and structures of the products were confirmed by (hnmr)-h-1, (cnmr)-c-13, and ftir spectroscopy and x-ray analysis; furthermore, a possible reaction mechanism was proposed. a polycarbonate was prepared from the bisphenol product and characterized as a model application, and thermogravimetric analysis (tga) showed that decomposition occurred in a single stage with the maximum rate of degradation at approximately 420 degrees c. differential scanning calorimetry (dsc) analysis showed that the glass transition temperature and melting peak of the polycarbonate were approximately 122 and 314 degrees c, respectively. the environmentally friendly characteristics of this study are featured by the integrated utilization of a biorenewable feedstock, a green biomacromolecule catalyst, and a green solvent for the preparation of valuable biochemicals and materials. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | renewable bisphenols ; diphenolic acid ; levulinic acid ; ionic liquids ; vanillin ; polymers ; hydrogenolysis ; conversion ; chemistry ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000352488300007 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146176]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, Peoples R China 2.Dalian Univ Technol, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315201, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qin,Huang, Wei,Chen, Peng,et al. Synthesis of Lignin-Derived Bisphenols Catalyzed by Lignosulfonic Acid in Water for Polycarbonate Synthesis[J]. chemcatchem,2015,7(7):1083-1089. |
| APA | Chen, Qin.,Huang, Wei.,Chen, Peng.,Peng, Chang.,Xie, Haibo.,...&Bao, Ming.(2015).Synthesis of Lignin-Derived Bisphenols Catalyzed by Lignosulfonic Acid in Water for Polycarbonate Synthesis.chemcatchem,7(7),1083-1089. |
| MLA | Chen, Qin,et al."Synthesis of Lignin-Derived Bisphenols Catalyzed by Lignosulfonic Acid in Water for Polycarbonate Synthesis".chemcatchem 7.7(2015):1083-1089. |
入库方式： OAI收割
来源：大连化学物理研究所
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