In situ growth and assembly of microporous aluminophosphate nanosheets into ordered architectures at low temperature and their enhanced catalytic performance
文献类型：期刊论文
| 作者 | Gao, Beibei1,2; Tian, Peng1; Li, Mingrun3; Yang, Miao1; Qiao, Yuyan1,2; Wang, Linying1; Xu, Shutao1; Liu, Zhongmin1,3 |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:15页码:7741-7749 |
| 英文摘要 | a low-temperature strategy to fabricate hierarchical aluminophosphate-based molecular sieves has been developed without the assistance of surfactants. the facile synthesis results in cylinder-like sapo-5 (afi) composed of oriented attached nanosheets with a thickness of 40-100 nm. the main exposed surface of the nanosheets is revealed by the saed pattern to be the {001} plane, implying a short path for molecular diffusion in the one-dimensional 12-membered ring channel. investigation on the crystallization process demonstrates that low temperature retards the crystal growth along the c-direction in sapo-5 and the ordered architecture forms via a nanosheet formation and oriented attachment process. the aggregated morphology of sapo-5 is template-dependent, which may be modified/changed by varying the template in the system. the low-temperature strategy is also successfully extended to the preparation of metal-containing aluminophosphate molecular sieves. the obtained meapo-5 (me = co, mn, and cr) and a novel cha/aei intergrowth coapo molecular sieve also possess hierarchical structures with nanosheet-assembled morphology. remarkably, the present self-assembled afi crystals exhibit an obvious improvement in catalytic reactions. this facile method provides a new way for the long-range organization of nanosized building blocks to fabricate hierarchical nanostructures. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; energy & fuels ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; energy & fuels ; materials science |
| 关键词[WOS] | hierarchical zeolite-beta ; cationic polymer ; crystalline zeolite ; molecular-sieve ; gold nanoparticles ; template ; nanostructures ; nanocrystals ; morphology ; polyelectrolyte |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000352441100010 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146178]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Beibei,Tian, Peng,Li, Mingrun,et al. In situ growth and assembly of microporous aluminophosphate nanosheets into ordered architectures at low temperature and their enhanced catalytic performance[J]. journal of materials chemistry a,2015,3(15):7741-7749. |
| APA | Gao, Beibei.,Tian, Peng.,Li, Mingrun.,Yang, Miao.,Qiao, Yuyan.,...&Liu, Zhongmin.(2015).In situ growth and assembly of microporous aluminophosphate nanosheets into ordered architectures at low temperature and their enhanced catalytic performance.journal of materials chemistry a,3(15),7741-7749. |
| MLA | Gao, Beibei,et al."In situ growth and assembly of microporous aluminophosphate nanosheets into ordered architectures at low temperature and their enhanced catalytic performance".journal of materials chemistry a 3.15(2015):7741-7749. |
入库方式： OAI收割
来源：大连化学物理研究所
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