Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation
文献类型：期刊论文
| 作者 | Wang, Xu; Lu, Sheng-mei; Li, Jun; Liu, Yan; Li, Can |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:5页码:2585-2589 |
| 英文摘要 | a series of chiral conjugated microporous polymers (cmps) based on the chiral (r)-binap ligand (binap-cmps) were synthesized with tunable bet surface areas. these solid catalysts show high activities and enantioselectivities for the asymmetric hydrogenation of beta-keto esters after coordination with ruthenium species. moreover, cmps can realize spatial isolation. through preventing the formation of dimers and trimers, binap-cmps show much higher activity than binap for the ir-catalyzed asymmetric hydrogenation of quinaldine. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | porous organic polymers ; miyaura coupling reaction ; n-heterocyclic carbene ; high-surface-area ; heterogeneous catalyst ; synthetic control ; framework ; networks ; nanoparticles ; epoxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000353641800006 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146222]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xu,Lu, Sheng-mei,Li, Jun,et al. Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation[J]. catalysis science & technology,2015,5(5):2585-2589. |
| APA | Wang, Xu,Lu, Sheng-mei,Li, Jun,Liu, Yan,&Li, Can.(2015).Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation.catalysis science & technology,5(5),2585-2589. |
| MLA | Wang, Xu,et al."Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation".catalysis science & technology 5.5(2015):2585-2589. |
入库方式： OAI收割
来源：大连化学物理研究所
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