Synergistic H4NI-AcOH Catalyzed Oxidation of the C-sp(3)-H Bonds of Benzylpyridines with Molecular Oxygen
文献类型：期刊论文
| 作者 | Ren, Lanhui1,2,3; Wang, Lianyue1,2; Lv, Ying1,2; Li, Guosong1,2; Gao, Shuang1,2 |
| 刊名 | organic letters
 |
| 出版日期 | 2015-05-01 |
| 卷号 | 17期号:9页码:2078-2081 |
| 英文摘要 | the oxidation of benzylpyridines forming benzoylpyridines was achieved based on a synergistic h4ni-acoh catalyst and molecular oxygen in high yield under solvent-free conditions. this is the first nonmetallic catalytic system for this oxidation transformation using molecular oxygen as the oxidant. the catalytic system has a wide scope of substrates and excellent chemoselectivity, and this procedure can also be scaled up. the study of a preliminary reaction mechanism demonstrated that the oxidation of the c-sp(3)-h bonds of benzylpyridines was promoted by the pyridinium salts formed by acoh and benzylpyridines. the synergistic effect of h4ni-acoh was also demonstrated by control experiments. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric hydrogenation ; selective oxidation ; copper ; ketones ; salts ; isoquinolines ; derivatives ; alcohols ; route |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354004400011 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146258]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Lanhui,Wang, Lianyue,Lv, Ying,et al. Synergistic H4NI-AcOH Catalyzed Oxidation of the C-sp(3)-H Bonds of Benzylpyridines with Molecular Oxygen[J]. organic letters,2015,17(9):2078-2081. |
| APA | Ren, Lanhui,Wang, Lianyue,Lv, Ying,Li, Guosong,&Gao, Shuang.(2015).Synergistic H4NI-AcOH Catalyzed Oxidation of the C-sp(3)-H Bonds of Benzylpyridines with Molecular Oxygen.organic letters,17(9),2078-2081. |
| MLA | Ren, Lanhui,et al."Synergistic H4NI-AcOH Catalyzed Oxidation of the C-sp(3)-H Bonds of Benzylpyridines with Molecular Oxygen".organic letters 17.9(2015):2078-2081. |
入库方式： OAI收割
来源：大连化学物理研究所
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