Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity
文献类型：期刊论文
| 作者 | Chen, Weidong1,2; Huang, Zhenguo; Wu, Guotao1; He, Teng1; Li, Zhao1; Chen, Juner1; Guo, Zaiping3; Liu, Huakun3; Chen, Ping1 |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:21页码:11411-11416 |
| 英文摘要 | for chemical hydrogen storage, capacity is one key criterion that has spurred intense efforts to investigate compounds with high hydrogen content. the guanidinium cation and the octahydrotriborate anion possess 6 h+ and 8 h-, respectively. the combination of these two ions yields guanidinium octahydrotriborate with 13.8 wt% hydrogen. this paper presents its facile synthesis, as confirmed by b-11 and h-1 nuclear magnetic resonance spectroscopy. the results show that guanidinium octahydrotriborate is an ionic liquid with a melting point below -10 degrees c, which makes it a possible injectable/pumpable hydrogen carrier. it decomposes selectively to hydrogen, in stark contrast to the formation of various boranes from related solid octahydrotriborates. the much improved h-2 purity can be ascribed to the more effective combination of h+ and h-, and the higher h+/h- ratio in liquid guanidinium octahydrotriborate. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; energy & fuels ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; energy & fuels ; materials science |
| 关键词[WOS] | n-h compounds ; thermal-decomposition ; ammonia-borane ; hypergolic fuels ; borohydride ; hydrolysis ; triborane ; hydrazine ; efficient ; hydrides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354952500030 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146267]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Univ Wollongong, Inst Superconducting & Elect Mat, North Wollongong, NSW 2522, Australia |
| 推荐引用方式 GB/T 7714 | Chen, Weidong,Huang, Zhenguo,Wu, Guotao,et al. Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity[J]. journal of materials chemistry a,2015,3(21):11411-11416. |
| APA | Chen, Weidong.,Huang, Zhenguo.,Wu, Guotao.,He, Teng.,Li, Zhao.,...&Chen, Ping.(2015).Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity.journal of materials chemistry a,3(21),11411-11416. |
| MLA | Chen, Weidong,et al."Guanidinium octahydrotriborate: an ionic liquid with high hydrogen storage capacity".journal of materials chemistry a 3.21(2015):11411-11416. |
入库方式： OAI收割
来源：大连化学物理研究所
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