Activity enhancement of Nafion resin: Vapor-phase carbonylation of dimethoxymethane over Nafion-silica composite
文献类型：期刊论文
| 作者 | Liu, Shiping1,2; Zhu, Wenliang1; Shi, Lei1; Liu, Hongchao1; Liu, Yong1; Ni, Youming1; Li, Lina1,2; Zhou, Hui1,2; Xu, Shutao1; He, Yanli1 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2015-05-01 |
| 卷号 | 497页码:153-159 |
| 关键词 | Dimethoxymethane Carbonylation Ethylene glycol Methyl methoxy acetate Nafion-silica composite |
| 英文摘要 | a kind of composite materials consisting of nano-sized nafion resin homogeneously dispersed in a high-surface silica matrix was prepared by sol-gel method and used as catalysts in the vapor-phase carbonylation reaction of dimethoxymethane for production of methylmethoxy acetate. these composite catalysts showed much higher catalytic activity in comparison with the original pure nafion resin catalyst. the remarkable improvement of catalytic performance was due to the increased accessibility of acid sites of nafion resin in the composite catalysts. the contents of nafion-h resin and silica precursors were found to have a great influence on the structure of the composite, resulting in different catalytic activity during dmm carbonylation reactions. furthermore, the comparison of the composite catalysts with high-silica h-y and h-beta zeolite catalysts demonstrated that the excellent catalytic performance is closely related to the higher acid strength and larger pores of nafion-silica composite materials. (c) 2015 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | solid acid catalysis ; surface-area ; state nmr ; zeolites ; sites ; nanocomposites ; formaldehyde ; solvation ; framework ; strength |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355052300017 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146268]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Shiping,Zhu, Wenliang,Shi, Lei,et al. Activity enhancement of Nafion resin: Vapor-phase carbonylation of dimethoxymethane over Nafion-silica composite[J]. applied catalysis a-general,2015,497:153-159. |
| APA | Liu, Shiping.,Zhu, Wenliang.,Shi, Lei.,Liu, Hongchao.,Liu, Yong.,...&Liu, Zhongmin.(2015).Activity enhancement of Nafion resin: Vapor-phase carbonylation of dimethoxymethane over Nafion-silica composite.applied catalysis a-general,497,153-159. |
| MLA | Liu, Shiping,et al."Activity enhancement of Nafion resin: Vapor-phase carbonylation of dimethoxymethane over Nafion-silica composite".applied catalysis a-general 497(2015):153-159. |
入库方式： OAI收割
来源：大连化学物理研究所
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