Postfunctionalization of BN-Embedded Polycyclic Aromatic Compounds for Fine-Tuning of Their Molecular Properties
文献类型：期刊论文
| 作者 | Wang, Xiao-Ye; Yang, Dong-Chu; Zhuang, Fang-Dong; Liu, Jia-Jie; Wang, Jie-Yu; Pei, Jian |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2015-06-08 |
| 卷号 | 21期号:24页码:8867-8873 |
| 关键词 | boron fluorescence nitrogen polycycles synthesis design |
| 英文摘要 | new bn-embedded, thiophene-fused, polycyclic aromatic compounds with planar geometry were designed and synthesized. the molecules showed excellent stability and chemical robustness. postfunctionalization on this skeleton was demonstrated with a series of electrophilic bromination, palladium-catalyzed cross-coupling, and knoevenagel condensation reactions. the skeleton remained intact during these late-stage transformations. the optical and electronic properties have been well tuned through incorporation of electron-rich and -deficient groups on the backbone. this work shows the great advantage of the postfunctionalization strategy on bn-containing polycyclic aromatic compounds for fast diversification and materials screening. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | field-effect transistors ; organic semiconductors ; conjugated materials ; pi-systems ; c-c ; performance ; heteroacenes ; polymers ; analogs ; design |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355287000031 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146284]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Ctr Soft Matter Sci & Engn, BNLMS,Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiao-Ye,Yang, Dong-Chu,Zhuang, Fang-Dong,et al. Postfunctionalization of BN-Embedded Polycyclic Aromatic Compounds for Fine-Tuning of Their Molecular Properties[J]. chemistry-a european journal,2015,21(24):8867-8873. |
| APA | Wang, Xiao-Ye,Yang, Dong-Chu,Zhuang, Fang-Dong,Liu, Jia-Jie,Wang, Jie-Yu,&Pei, Jian.(2015).Postfunctionalization of BN-Embedded Polycyclic Aromatic Compounds for Fine-Tuning of Their Molecular Properties.chemistry-a european journal,21(24),8867-8873. |
| MLA | Wang, Xiao-Ye,et al."Postfunctionalization of BN-Embedded Polycyclic Aromatic Compounds for Fine-Tuning of Their Molecular Properties".chemistry-a european journal 21.24(2015):8867-8873. |
入库方式： OAI收割
来源：大连化学物理研究所
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