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Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

文献类型:期刊论文

作者De Baerdemaeker, Trees1; Feyen, Mathias2; Mueller, Ulrich2; Yilmaz, Bilge3; Xiao, Feng-Shou4; Zhang, Weiping5; Yokoi, Toshiyuki6; Bao, Xinhe7; Gies, Hermann8; De Vos, Dirk E.1
刊名acs catalysis
出版日期2015-06-01
卷号5期号:6页码:3393-3397
关键词1 ethanol zinc silicate hemimorphite heterogeneous catalysis silica impregnation 3-butadiene
英文摘要silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. the combination of hf(iv) and zn(ii) resulted in a stable, active, and selective catalyst in which the zn(ii) effectively suppressed the dehydration activity of hf(iv); the catalyst preparation method plays a crucial role. using the crystalline zn-silicate hemimorphite as an alternative zn(ii) source proved to be even more successful in suppressing ethanol dehydration.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]magnesium-oxide ; metal-oxides ; butadiene ; hydroxyapatite ; transformation ; selectivity ; basicity ; acetone ; lebedev
收录类别SCI
语种英语
WOS记录号WOS:000355964300025
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/146308]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium
2.BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany
3.BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA
4.Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China
5.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
6.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
7.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
8.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
推荐引用方式
GB/T 7714
De Baerdemaeker, Trees,Feyen, Mathias,Mueller, Ulrich,et al. Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene[J]. acs catalysis,2015,5(6):3393-3397.
APA De Baerdemaeker, Trees.,Feyen, Mathias.,Mueller, Ulrich.,Yilmaz, Bilge.,Xiao, Feng-Shou.,...&De Vos, Dirk E..(2015).Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene.acs catalysis,5(6),3393-3397.
MLA De Baerdemaeker, Trees,et al."Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene".acs catalysis 5.6(2015):3393-3397.

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来源:大连化学物理研究所

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