Two-step thermochemical cycles for CO2 splitting on Zr-doped cobalt ferrite supported on silica
文献类型：期刊论文
| 作者 | Tong, Jinhui; Jiang, Qingqing; Chen, Zhenpan; Jiang, Zongxuan; Li, Can |
| 刊名 | solar energy
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 116页码:133-143 |
| 关键词 | Two-step thermochemical cycle CO2 splitting Zr-doped ferrite |
| 英文摘要 | silica-supported zr-doped cobalt ferrite complex oxides, co1-2xzrxfe2o4/sio2 (0 <= x <= 0.15) were prepared via a simple sol-gel auto-combustion method using aqueous silica colloid as the silica source. the products were used as reactive materials in two-step thermochemical cycles for co2 splitting. compared to undoped cobalt ferrite, the zr-doped ones can significantly enhance the rates of the reduction and oxidation steps as well as the yields of co. the zr-doped sample also showed greater recyclability than the undoped one. when the sample co0.8zr0.1fe2o4/sio2 was used as reactive material, the average production of 24.4 ml/g(ferrite) for o-2 and 40.2 ml/g(ferrite) for co were obtained after 20 cycles at 1400 and 1100 degrees c respectively. a kinetic analysis indicated the apparent activation energy in the co2 splitting step over co0.8zr0.1fe2o4/sio2 is 118.0 +/- 1.2 kj/mol, while it is 133.0 +/- 2.1 kj/mol for cofe2o4/sio2. (c) 2015 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | energy & fuels |
| 研究领域[WOS] | energy & fuels |
| 关键词[WOS] | feo/fe3o4 redox reactions ; solar hydrogen-production ; carbon-dioxide ; nonstoichiometric ceria ; reactive material ; kinetic-analysis ; solid-solutions ; water ; reduction ; zn/zno |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356198300013 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146331]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Jinhui,Jiang, Qingqing,Chen, Zhenpan,et al. Two-step thermochemical cycles for CO2 splitting on Zr-doped cobalt ferrite supported on silica[J]. solar energy,2015,116:133-143. |
| APA | Tong, Jinhui,Jiang, Qingqing,Chen, Zhenpan,Jiang, Zongxuan,&Li, Can.(2015).Two-step thermochemical cycles for CO2 splitting on Zr-doped cobalt ferrite supported on silica.solar energy,116,133-143. |
| MLA | Tong, Jinhui,et al."Two-step thermochemical cycles for CO2 splitting on Zr-doped cobalt ferrite supported on silica".solar energy 116(2015):133-143. |
入库方式： OAI收割
来源：大连化学物理研究所
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