A new zeolite formed from interlayer expansion of the precursor COK-5
文献类型：期刊论文
| 作者 | Bian, Chaoqun1; Wu, Qinming1; Zhang, Jian1; Chen, Fang1; Pan, Shuxiang1; Wang, Liang1; Meng, Xiangju1; Mueller, Ulrich2; Feyen, Mathias2; Yilmaz, Bilge3 |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2015-09-15 |
| 卷号 | 214页码:204-209 |
| 关键词 | Interlayer expansion Zeolite Lamellar precursor COK-5 DCDMS |
| 英文摘要 | the layered silicate cok-5 has been used for an interlayer expansion reaction with dichlorodimethylsilane (dcdms) at 180 degrees c to interconnect neighboring layers, yielding a new and crystalline microporous framework. the samples containing the methyl functional groups in the as-made form and having oh groups in the calcined form were designed as coe-5 and calcined coe-5. these samples were characterized with x-ray diffraction (xrd), n-2 sorption isotherms, inductively coupled plasma optical emission spectrometry (icp-oes), infrared spectroscopy (ir), high-resolution transmission electron micrograph (hrtem), thermogravimetry-differential thermal analysis (tg-dta), and si-29 and c-13 solid-state magic-angle spinning nuclear magnetic resonance (mas nmr), as well as the contact angle techniques. xrd patterns and hrtem images suggest that the sample interlayer spacing has been expanded by nearly 0.5 angstrom. the n-2 sorption isotherms of the materials show the bet surface areas are 165 m(2)/g for coe-5 and 340 m(2)/g for calcined coe-5. si-29 and c-13 mas nmr as well as ir spectroscopy confirm the insertion of the linker group -si(ch3)(2)- connecting neighboring layers. interestingly, calcined coe-5 shows enhanced catalytic performance in the acetalisation of glycerol with acetone to produce solketal, compared with cok-5. (c) 2015 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | fer-type zeolite ; crystal-structure ; lamellar precursor ; topotactic conversion ; adsorption properties ; layered precursor ; expanded zeolite ; molecular-sieve ; silicate rub-36 ; channel systems |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356749900027 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146332]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310007, Zhejiang, Peoples R China 2.BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany 3.BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA 4.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany 5.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 7.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Leuven, Belgium 8.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 227, Japan |
| 推荐引用方式 GB/T 7714 | Bian, Chaoqun,Wu, Qinming,Zhang, Jian,et al. A new zeolite formed from interlayer expansion of the precursor COK-5[J]. microporous and mesoporous materials,2015,214:204-209. |
| APA | Bian, Chaoqun.,Wu, Qinming.,Zhang, Jian.,Chen, Fang.,Pan, Shuxiang.,...&Xiao, Feng-Shou.(2015).A new zeolite formed from interlayer expansion of the precursor COK-5.microporous and mesoporous materials,214,204-209. |
| MLA | Bian, Chaoqun,et al."A new zeolite formed from interlayer expansion of the precursor COK-5".microporous and mesoporous materials 214(2015):204-209. |
入库方式： OAI收割
来源：大连化学物理研究所
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