Catalytic hydrogenation of carbon monoxide over Rh-Mn-Li/SiO2 catalyst for the synthesis of C2+ oxygenates: the remarkable effect of urea on the particle size of Rh
文献类型：期刊论文
| 作者 | Xue, Fei1,3; Ding, Yunjie1,2; Chen, Weimiao1; Song, Xiangen1; Cheng, Xianbo1 |
| 刊名 | reaction kinetics mechanisms and catalysis
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 115期号:2页码:625-634 |
| 关键词 | Urea Carbon monoxide hydrogenation C2+ oxygenates Supported Rh catalyst Structure-sensitive reaction |
| 英文摘要 | a series of rh-mn-li/sio2 catalysts were prepared by the impregnation of a silica support with solutions containing metal precursors with different amounts of urea. catalyst performance was investigated by the hydrogenation of carbon monoxide. the catalysts were characterized by x-ray diffraction, transmission electron microscopy, hydrogen chemisorption, diffuse reflectance ultraviolet-visible (dr uv-vis) spectroscopy, and thermogravimetric analysis. the results revealed that the amount of urea had a significant effect on the particle size of rh, which increased from approximately 2-5 nm with the increase in urea loading from 0 to 2.0 wt%. dr uv-vis spectra indicated that the increase in the rh particle size with increasing urea loading might be attributed to the coordination of rh3+ with urea or its derivatives during calcination. at a urea loading of 1.0 wt%, the particle size of rh was 3.7 nm, and the space time yield of c2+ oxygenates reached a maximum of 560.0 g kg(-1) h(-1). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | supported rhodium catalysts ; pressure co hydrogenation ; fischer-tropsch synthesis ; ethanol-production ; synthesis gas ; syngas ; selectivity ; performance ; promotion ; hydroformylation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000358170200015 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146396]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Fei,Ding, Yunjie,Chen, Weimiao,et al. Catalytic hydrogenation of carbon monoxide over Rh-Mn-Li/SiO2 catalyst for the synthesis of C2+ oxygenates: the remarkable effect of urea on the particle size of Rh[J]. reaction kinetics mechanisms and catalysis,2015,115(2):625-634. |
| APA | Xue, Fei,Ding, Yunjie,Chen, Weimiao,Song, Xiangen,&Cheng, Xianbo.(2015).Catalytic hydrogenation of carbon monoxide over Rh-Mn-Li/SiO2 catalyst for the synthesis of C2+ oxygenates: the remarkable effect of urea on the particle size of Rh.reaction kinetics mechanisms and catalysis,115(2),625-634. |
| MLA | Xue, Fei,et al."Catalytic hydrogenation of carbon monoxide over Rh-Mn-Li/SiO2 catalyst for the synthesis of C2+ oxygenates: the remarkable effect of urea on the particle size of Rh".reaction kinetics mechanisms and catalysis 115.2(2015):625-634. |
入库方式： OAI收割
来源：大连化学物理研究所
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