Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes
文献类型：期刊论文
| 作者 | Zhou, Xukai; Yu, Songjie; Qi, Zisong; Li, Xingwei |
| 刊名 | science china-chemistry
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 58期号:8页码:1297-1301 |
| 关键词 | rhodium(III) C-H activation annulation oxime alkyne |
| 英文摘要 | rhodium(iii)-catalyzed coupling between ketoximes and alkynes via c-h activation and annulation typically followed the [4+2] selectivity to afford isoquinolines. by designing alkynes bearing a highly electron-withdrawing group and under substrate control, we have successfully switched the selectivity of the coupling between oximes and alkynes to the alternative [3+2] annulation, leading to the efficient synthesis of indenamines. this process features good regioselectivity for both substrates, high efficiency, broad substrate scope, and excellent functional group tolerance. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h activation ; polymer solar-cells ; bond activation ; internal alkynes ; aromatic ketimines ; indene frameworks ; derivatives ; cyclization ; ruthenium ; functionalization |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000358605500009 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146414]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xukai,Yu, Songjie,Qi, Zisong,et al. Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes[J]. science china-chemistry,2015,58(8):1297-1301. |
| APA | Zhou, Xukai,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes.science china-chemistry,58(8),1297-1301. |
| MLA | Zhou, Xukai,et al."Rhodium(III)-catalyzed [3+2] annulative coupling between oximes and electron-deficient alkynes".science china-chemistry 58.8(2015):1297-1301. |
入库方式： OAI收割
来源：大连化学物理研究所
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