Metathesis of 1-Butene to Propene over Mo/Al2O3@SBA-15: Influence of Alumina Introduction Methods on Catalytic Performance
文献类型：期刊论文
| 作者 | Zhang, Dazhou1,2; Li, Xiujie1; Liu, Shenglin1; Zhu, Xiangxue1; Chen, Fucun1; Xu, Longya1 |
| 刊名 | chemistry-an asian journal
 |
| 出版日期 | 2015-08-01 |
| 卷号 | 10期号:8页码:1647-1659 |
| 关键词 | alumina metathesis molybdenum propene sba-15 |
| 英文摘要 | a series of mo-based catalysts for 1-butene metathesis to propene were prepared by supporting mo species on sba-15 premodified with alumina. the effects of the method of introduction of the alumina guest to the host sba-15 on the location of the mo species and the corresponding metathesis activity were studied. as revealed by n-2 adsorption isotherms and tem results, well-dispersed alumina was formed on the pore walls of sba-15 if the ammonia/water vapor induced hydrolysis (nih) method was employed. the mo species preferentially interacted with alumina instead of sba-15, as evidenced by x-ray photoelectron spectroscopy, time-of-flight secondary-ion mass spectrometry, and ir spectroscopy of adsorbed pyridine. furthermore, new bronsted acid sites favorable for the dispersion of the mo species and low-temperature metathesis activity were generated as a result of the effective synergy between the alumina and sba-15. the mo/al2o3@sba-15 catalyst prepared by the nih method showed higher metathesis activity and stability under the conditions of 120 degrees c, 0.1mpa, and 1.5h(-1) than catalysts prepared by other methods. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | mesoporous molecular-sieves ; olefin metathesis ; gamma-alumina ; molybdenum oxides ; active-sites ; sol-gel ; sba-15 ; silica ; surface ; support |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000358793000008 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146434]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Dazhou,Li, Xiujie,Liu, Shenglin,et al. Metathesis of 1-Butene to Propene over Mo/Al2O3@SBA-15: Influence of Alumina Introduction Methods on Catalytic Performance[J]. chemistry-an asian journal,2015,10(8):1647-1659. |
| APA | Zhang, Dazhou,Li, Xiujie,Liu, Shenglin,Zhu, Xiangxue,Chen, Fucun,&Xu, Longya.(2015).Metathesis of 1-Butene to Propene over Mo/Al2O3@SBA-15: Influence of Alumina Introduction Methods on Catalytic Performance.chemistry-an asian journal,10(8),1647-1659. |
| MLA | Zhang, Dazhou,et al."Metathesis of 1-Butene to Propene over Mo/Al2O3@SBA-15: Influence of Alumina Introduction Methods on Catalytic Performance".chemistry-an asian journal 10.8(2015):1647-1659. |
入库方式： OAI收割
来源：大连化学物理研究所
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