Tuning the optoelectronic properties of dual-acceptor based low-bandgap ambipolar polymers by changing the thiophene-bridge length
文献类型：期刊论文
| 作者 | An, Cunbin1; Marszalek, Tomasz1; Guo, Xin1,2; Puniredd, Sreenivasa Reddy1; Wagner, Manfred1; Pisula, Wojciech1,3; Baumgarten, Martin1 |
| 刊名 | polymer chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:34页码:6238-6245 |
| 英文摘要 | three very-low-bandgap dual-acceptor based polymers containing diketopyrrolopyrrole (dpp) and a thiadiazoloquinoxaline (tq) derivative were prepared. both acceptors in these polymers were separated by one, two and three thiophenes. by only inserting one thiophene between dpp and benzodithiophene condensed tq, the polymer pdpp-t-tq shows a very low optical bandgap of 0.60 ev with an electron affinity of -4.23 ev. optical and electrochemical bandgaps of the polymers were enlarged with increasing the thiophene-bridge length between both acceptors. giwaxs measurements confirmed that the polymer with three thiophene bridges (pdpp-3t-tq) showed an ordered arrangement of the crystallites, providing the best ambipolar device performance among these polymers. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | field-effect transistors ; thin-film transistors ; high-performance ambipolar ; conjugated polymers ; organic photovoltaics ; electronic-properties ; energy-level ; solar-cells ; donor ; copolymer |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000360047700015 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146477]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Max Planck Inst Polymer Res, D-55128 Mainz, Germany 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Lodz Univ Technol, Fac Chem, Dept Mol Phys, PL-90924 Lodz, Poland |
| 推荐引用方式 GB/T 7714 | An, Cunbin,Marszalek, Tomasz,Guo, Xin,et al. Tuning the optoelectronic properties of dual-acceptor based low-bandgap ambipolar polymers by changing the thiophene-bridge length[J]. polymer chemistry,2015,6(34):6238-6245. |
| APA | An, Cunbin.,Marszalek, Tomasz.,Guo, Xin.,Puniredd, Sreenivasa Reddy.,Wagner, Manfred.,...&Baumgarten, Martin.(2015).Tuning the optoelectronic properties of dual-acceptor based low-bandgap ambipolar polymers by changing the thiophene-bridge length.polymer chemistry,6(34),6238-6245. |
| MLA | An, Cunbin,et al."Tuning the optoelectronic properties of dual-acceptor based low-bandgap ambipolar polymers by changing the thiophene-bridge length".polymer chemistry 6.34(2015):6238-6245. |
入库方式： OAI收割
来源：大连化学物理研究所
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