Solvent Mediation for Enhanced Separation of 5-Hydroxymethylfurfural from 1-Butyl-3-Methylimidazolium Chloride
文献类型：期刊论文
| 作者 | Zhou, Jinxia1,2; Huang, Tingyu1; Zhao, Yuling3; Xia, Zhi1; Xu, Zhanwei1; Jia, Songyan1; Wang, Jianji3; Zhang, Z. Conrad1 |
| 刊名 | industrial & engineering chemistry research
 |
| 出版日期 | 2015-08-19 |
| 卷号 | 54期号:32页码:7977-7983 |
| 英文摘要 | ionic liquids have been widely studied as effective reaction media for the conversion of glucose or cellulose to 5-hydroxymethhylfurfural (5-hmf). however, the recovery of 5-hmf from ionic liquids, typically carried out by extraction, has been encountered with very low extraction efficiency, which limited the reusability of the solvents. through this work, based on the model biphasic system that consists of 1-butyl-3-methylimidazolium chloride ([bmim] co as the ionic liquid phase and methyl isobutyl ketone (mibk) as the extractant phase, the dominant force that suppresses the extraction efficiency of 5-hmf was identified as being the strong hydrogen bonding between 5-hmf and [bmim]cl. solvent mediation with functional promoters have been established as a new strategy to shift this force, resulting in improved extraction efficiency of 5-hmf from the ionic liquid. for example, with ethanol as a promoter, the distribution coefficient of 5-hmf was about 10 times higher than that without a promoter. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | engineering, chemical |
| 研究领域[WOS] | engineering |
| 关键词[WOS] | ionic liquids ; molecular-dynamics ; extraction ; conversion ; cellulose ; fructose ; simulation ; proteins ; glucose ; biomass |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000359962300022 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146481]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Dalian Univ, Coll Environm & Chem Engn, Dalian 116012, Peoples R China 3.Henan Normal Univ, Sch Chem & Chem Engn, Key Lab Green Chem Media & React, Minist Educ, Xinxiang, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Jinxia,Huang, Tingyu,Zhao, Yuling,et al. Solvent Mediation for Enhanced Separation of 5-Hydroxymethylfurfural from 1-Butyl-3-Methylimidazolium Chloride[J]. industrial & engineering chemistry research,2015,54(32):7977-7983. |
| APA | Zhou, Jinxia.,Huang, Tingyu.,Zhao, Yuling.,Xia, Zhi.,Xu, Zhanwei.,...&Zhang, Z. Conrad.(2015).Solvent Mediation for Enhanced Separation of 5-Hydroxymethylfurfural from 1-Butyl-3-Methylimidazolium Chloride.industrial & engineering chemistry research,54(32),7977-7983. |
| MLA | Zhou, Jinxia,et al."Solvent Mediation for Enhanced Separation of 5-Hydroxymethylfurfural from 1-Butyl-3-Methylimidazolium Chloride".industrial & engineering chemistry research 54.32(2015):7977-7983. |
入库方式： OAI收割
来源：大连化学物理研究所
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