Acetone-activated polyimide electrospun nanofiber membrane for thin-film microextraction and thermal desorption-gas chromatography-mass spectrometric analysis of phenols in environmental water
文献类型：期刊论文
| 作者 | Li, Shenghong1,2; Wu, Dapeng1; Yan, Xiaohui1; Guan, Yafeng1 |
| 刊名 | journal of chromatography a
 |
| 出版日期 | 2015-09-11 |
| 卷号 | 1411页码:1-8 |
| 关键词 | Polyimide Electrospun Nanofiber Acetone Thin film microextraction (TFME) Phenols |
| 英文摘要 | in this work, a polyimide nanofiber membrane was electrospun and applied as sorbent for thin film microextraction (tfme). after tfme of phenols in water samples, direct thermal desorption of the sorbent at 300 degrees c followed by gas chromatography-mass spectrometric (td-gc-ms) analysis was carried out. the extraction efficiency of tfme was enhanced by 6-12 times for phenols after activation with acetone. the positive effect of acetone activation was correlated to the increased hydrophilicity of the membrane. extraction parameters, including mass of nanofiber membrane, ph value, nacl concentration and extraction time, were optimized. under optimal conditions, the lods and loqs for analysis of phenols in spiked purified water were 0.0006-0.008 and 0.002-0.025 mu g l-1, respectively. the linearity range was more than two orders of magnitude (r > 0.99). the rsds of intra-batch and inter-batch were 4.3-7.4% and 2.7-10.6% (n = 3). finally the method was applied to real samples, including tap water, sea water, and waste water. these results indicate that the polyimide nanofiber membrane is a promising candidate as tfme sorbent for determination of polar analytes in water samples coupled with td-gc-ms. (c) 2015 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | solid-phase microextraction ; bar sorptive extraction ; polycyclic aromatic-hydrocarbons ; personal care products ; aqueous samples ; coated fiber ; chlorophenols ; coatings ; sorbent ; liquid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000361075600001 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146515]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shenghong,Wu, Dapeng,Yan, Xiaohui,et al. Acetone-activated polyimide electrospun nanofiber membrane for thin-film microextraction and thermal desorption-gas chromatography-mass spectrometric analysis of phenols in environmental water[J]. journal of chromatography a,2015,1411:1-8. |
| APA | Li, Shenghong,Wu, Dapeng,Yan, Xiaohui,&Guan, Yafeng.(2015).Acetone-activated polyimide electrospun nanofiber membrane for thin-film microextraction and thermal desorption-gas chromatography-mass spectrometric analysis of phenols in environmental water.journal of chromatography a,1411,1-8. |
| MLA | Li, Shenghong,et al."Acetone-activated polyimide electrospun nanofiber membrane for thin-film microextraction and thermal desorption-gas chromatography-mass spectrometric analysis of phenols in environmental water".journal of chromatography a 1411(2015):1-8. |
入库方式： OAI收割
来源：大连化学物理研究所
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