Porous carbon in catalytic transformation of cellulose
文献类型：期刊论文
| 作者 | Zhao, Xiaochen; Xu, Jinming; Wang, Aiqin; Zhang, Tao |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2015-09-01 |
| 卷号 | 36期号:9页码:1419-1427 |
| 关键词 | Biomass conversion Catalysis Porous carbon Activated carbon Mesoporous carbon Cellulose |
| 英文摘要 | the application of porous carbon in catalytic transformation of cellulose has received considerable interest owing to increasing energy and environmental pressures. in this mini-review, we first outline the featured properties of porous carbon in catalytic cellulose transformation in terms of porosities and surface functionalities. an interconnected hierarchical structure and enrichment of mesopores are highly desired for reactant, intermediate, and product diffusion; while hydrophilic surfaces are favored in aqueous phase transformation and certain acidic oxygen functionalities play a role of acid sites as well as enhancing the adsorption of feedstock via 1,4-glycosidic bonds. we then summarize specific reactions in cellulose transformation in the order of hydrolysis and hydrolytic hydrogenation. in the hydrolysis of cellulose, porous carbon is generally used as a solid acid by taking advantage of its enriched oxygen functionalities, while in the hydrolytic hydrogenation, carbon serves as the support of bifunctional catalysts with active acidic sites. finally, the synthesis and potential application of specific novel porous carbon materials, such as heteroatom-modified porous carbon and mesoporous carbon composites, are highlighted. (c) 2015, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | supported ruthenium catalysts ; ordered mesoporous carbons ; ethylene-glycol ; hydrolytic hydrogenation ; amorphous-carbon ; sugar alcohols ; aqueous-phase ; doped carbon ; solid acid ; conversion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000361084300004 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146520]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,et al. Porous carbon in catalytic transformation of cellulose[J]. chinese journal of catalysis,2015,36(9):1419-1427. |
| APA | Zhao, Xiaochen,Xu, Jinming,Wang, Aiqin,&Zhang, Tao.(2015).Porous carbon in catalytic transformation of cellulose.chinese journal of catalysis,36(9),1419-1427. |
| MLA | Zhao, Xiaochen,et al."Porous carbon in catalytic transformation of cellulose".chinese journal of catalysis 36.9(2015):1419-1427. |
入库方式： OAI收割
来源：大连化学物理研究所
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