Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system
文献类型：期刊论文
| 作者 | Li, Changzhi1; Cai, Haile1; Zhang, Bo1; Li, Weizhen1; Pei, Guangxian1,2; Dai, Tao1,2; Wang, Aiqin1,3; Zhang, Tao1,3 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2015-09-01 |
| 卷号 | 36期号:9页码:1638-1646 |
| 关键词 | Biomass Ionic liquids 2 2 5-Hydroxylmethylfufural Fructose Biofuel 5-Dimethylfuran 5-Dimethyltetrahydrofuran |
| 英文摘要 | the one-pot catalytic transformation of biomass to useful products is desirable for saving cost and time. the integration of the various reaction steps need to address the presence of incompatible reaction conditions and numerous side reactions. we report a novel process for the one-pot production of furan-based fuels, 2,5-dimethylfuran (dmf) and 2,5-dihmethyltetrahydrofuran (dmtf), from fructose by optimizing the synergic effect of an ionic liquid promoted ru/c catalyst and the solvent effect. the dehydration of fructose and subsequent in situ hydrodeoxygenation of hmf to dmf and dmtf on ru/c were enhanced by the use of an ionic liquid and a biphasic [bmim]cl/thf solvent. elemental analysis, x-ray photoelectron spectroscopy, raman spectroscopy and h2-temperature programmed reduction-mass spectroscopy characterization showed that the ionic liquid modified the electronic density of the ru species to favor hmf in situ hydrodeoxygenation. moreover, thf served as a reaction-extraction solvent that extracted dmf and dmtf from the reaction layer to avoid further side reactions. a rational design that gave enhancement of the catalytic performance and product protection provides a promising strategy for the one-pot conversion of biomass to desired fuels. (c) 2015, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | efficient production ; ethylene-glycol ; biomass ; chemicals ; cellulose ; 2,5-dimethylfuran ; conversion ; catalysts ; insight ; transformation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000361084300026 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146526]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Changzhi,Cai, Haile,Zhang, Bo,et al. Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system[J]. chinese journal of catalysis,2015,36(9):1638-1646. |
| APA | Li, Changzhi.,Cai, Haile.,Zhang, Bo.,Li, Weizhen.,Pei, Guangxian.,...&Zhang, Tao.(2015).Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system.chinese journal of catalysis,36(9),1638-1646. |
| MLA | Li, Changzhi,et al."Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent system".chinese journal of catalysis 36.9(2015):1638-1646. |
入库方式： OAI收割
来源：大连化学物理研究所
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