Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines
文献类型：期刊论文
| 作者 | Chen, Bo1,2; Wang, Lianyue1; Gao, Shuang1 |
| 刊名 | acs catalysis
 |
| 出版日期 | 2015-10-01 |
| 卷号 | 5期号:10页码:5851-5876 |
| 关键词 | aerobic oxidation alcohols amities catalysis imines |
| 英文摘要 | imines as valuable intermediates are widely applied in pharmaceutical syntheses and organic transformation. however, the traditional imine synthesis involves unstable aldehydes, dehydrating agents, and lewis acid catalysts. the topic of this review is focused on three new approaches, namely, the cross-coupling of alcohols with amines, the self-coupling of primarily amines, and the oxidative dehydrogenation of secondary amines, utilizing much more readily available starting materials and green oxidant (o-2/air) to furnish the imine products. the related catalysts are classified into metal, metal-free, photo-, and bioinspired catalysts. particular emphasis is placed on the high-active, low-cost, and versatile catalysts; key factors that affect the catalytic activity and reaction mechanisms are also highlighted. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | one-pot synthesis ; solvent-free conditions ; supported gold nanoparticles ; catalyzed direct synthesis ; metal-organic frameworks ; highly efficient ; secondary-amines ; selective oxidation ; ambient conditions ; tandem synthesis |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000362391500022 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146571]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Bo,Wang, Lianyue,Gao, Shuang. Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines[J]. acs catalysis,2015,5(10):5851-5876. |
| APA | Chen, Bo,Wang, Lianyue,&Gao, Shuang.(2015).Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines.acs catalysis,5(10),5851-5876. |
| MLA | Chen, Bo,et al."Recent Advances in Aerobic Oxidation of Alcohols and Amines to Imines".acs catalysis 5.10(2015):5851-5876. |
入库方式： OAI收割
来源：大连化学物理研究所
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