Electronic promoter or reacting species? The role of LiNH2 on Ru in catalyzing NH3 decomposition
文献类型：期刊论文
| 作者 | Guo, Jianping1,2; Chen, Zheng3,4; Wu, Anan3,4; Chang, Fei1,2; Wang, Peikun1,2; Hu, Daqiang1; Wu, Guotao1; Xiong, Zhitao1; Yu, Pei1,2; Chen, Ping1,5 |
| 刊名 | chemical communications
 |
| 出版日期 | 2015 |
| 卷号 | 51期号:82页码:15161-15164 |
| 英文摘要 | linh2 decomposes to nh3 rather than n-2 and h-2 because of a severe kinetic barrier in nhx (x = 1, 2) coupling. in the presence of ru, however, a drastic enhancement in n-2 and h-2 formation is obtained, which enables the linh2-ru composite to act as a highly active catalyst for nh3 decomposition. experimental and theoretical investigations indicate that li creates a nhx-rich environment and ru mediates the electron transfer facilitating nhx coupling. a strategy in catalytic material design is thus proposed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | cox-free hydrogen ; ammonia decomposition ; ruthenium catalyst ; lithium imide ; generation ; storage ; cesium ; potassium ; nitrides ; barium |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000362579000018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146586]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 4.Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Jianping,Chen, Zheng,Wu, Anan,et al. Electronic promoter or reacting species? The role of LiNH2 on Ru in catalyzing NH3 decomposition[J]. chemical communications,2015,51(82):15161-15164. |
| APA | Guo, Jianping.,Chen, Zheng.,Wu, Anan.,Chang, Fei.,Wang, Peikun.,...&Chen, Ping.(2015).Electronic promoter or reacting species? The role of LiNH2 on Ru in catalyzing NH3 decomposition.chemical communications,51(82),15161-15164. |
| MLA | Guo, Jianping,et al."Electronic promoter or reacting species? The role of LiNH2 on Ru in catalyzing NH3 decomposition".chemical communications 51.82(2015):15161-15164. |
入库方式： OAI收割
来源：大连化学物理研究所
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