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High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity
文献类型：期刊论文
| 作者 | Yang, Hui1,3; Zhang, Shengliang2,3; Han, Liheng1; Zhang, Zhou1; Xue, Zheng1; Gao, Juan1,3; Li, Yongjun1; Huang, Changshui2; Yi, Yuanping1; Liu, Huibiao1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2016-03-02 |
| 卷号 | 8期号:8页码:5366-5375 |
| 关键词 | 2D COF polyporphyrin high conductive lithium storage high capacity |
| 英文摘要 | A high conductive 2D COF polyporphyrin (TThPP) linked by 4-thiophenephenyl groups was synthesized through an in situ chemical oxidative polymerization on the surface of copper foil. The TThPP films were used as the anode of lithium-ion battery, which exhibited high specific capacities, excellent rate performances, and long cycle lives due to the alignment of 2D polyporphyrin nanosheets, and they (i) can highly efficiently adsorb Li atoms, (ii) have short-ended paths for the fast lithium ion diffusion, and (iii) open nanopores holding electrolyte. The reversible capacity is up to 666 mAh/g. This is the first example of an organic 2D COF for an anode of lithium-ion battery and represents an important step toward the use of COFs in the next-generation high-performance lithium ion battery. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | ION BATTERIES ; PHOTOPHYSICAL PROPERTIES ; PORPHYRIN ARRAYS ; HYDROGEN STORAGE ; THIN-FILMS ; PERFORMANCE ; CATHODE ; CRYSTALLINE ; POLYMERS ; ELECTRON |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000371453600036 |
| 公开日期 | 2016-05-17 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/8059]  |
| 专题 | 青岛生物能源与过程研究所_新型能源碳素材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hui,Zhang, Shengliang,Han, Liheng,et al. High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(8):5366-5375. |
| APA | Yang, Hui.,Zhang, Shengliang.,Han, Liheng.,Zhang, Zhou.,Xue, Zheng.,...&Li, Yuliang.(2016).High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity.ACS APPLIED MATERIALS & INTERFACES,8(8),5366-5375. |
| MLA | Yang, Hui,et al."High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity".ACS APPLIED MATERIALS & INTERFACES 8.8(2016):5366-5375. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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