A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols
文献类型：期刊论文
| 作者 | Pan, Bing1; Liu, Bo1; Yue, Erlin2; Liu QB(刘庆彬)1; Yang, Xinzheng2; Wang, Zheng1,2; Sun WH(孙文华)2,3 |
| 刊名 | ACS Catalysis
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:2页码:1247-1253 |
| 关键词 | ruthenium catalyst coupling cyclization N-heterocyclic compound AD reaction high efficiency |
| ISSN号 | 2155-5435 |
| 通讯作者 | 刘庆彬 ; 孙文华 |
| 英文摘要 | The ruthenium complex (8-(2-diphenylphosphinoethyl)aminotrihydroquinolinyl)(carbonyl)(hydrido)ruthenium chloride exhibited extremely high efficiency toward the coupling cyclization of γ-amino alcohols with secondary alcohols. The corresponding products, pyridine or quinoline derivatives, are obtained in good to high isolated yields. On comparison with literature catalysts whose noble-metal loading with respect to γ-amino alcohols reached 0.5–1.0 mol % for Ru and a record lowest of 0.04 mol % for Ir, the current catalyst achieves the same efficiency with a loading of 0.025 mol % for Ru. The mechanism of acceptorless dehydrogenative condensation (ADC) was proposed on the basis of DFT calculations; in addition, the reactive intermediates were determined by GC-MS, NMR, and single-crystal X-ray diffraction. The catalytic process is potentially suitable for industrial applications. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Nos. 21476060;21374123;U1362204;21373228);the Nature Science Foundation of Hebei Province (No. B2014205049), China |
| 语种 | 英语 |
| WOS记录号 | WOS:000369774900086 |
| 源URL | [http://210.77.64.217/handle/362003/19732]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Bing,Liu, Bo,Yue, Erlin,et al. A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols[J]. ACS Catalysis,2016,6(2):1247-1253. |
| APA | Pan, Bing.,Liu, Bo.,Yue, Erlin.,Liu QB.,Yang, Xinzheng.,...&Sun WH.(2016).A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols.ACS Catalysis,6(2),1247-1253. |
| MLA | Pan, Bing,et al."A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols".ACS Catalysis 6.2(2016):1247-1253. |
入库方式： OAI收割
来源：兰州化学物理研究所
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