中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation

文献类型:期刊论文

作者Hou FJ(侯风君)1,2; Zhao HH(赵华华)1; Zhao J(赵军)1; Yang J(杨建)1; Yan L(闫亮)1; Song HL(宋焕玲)1; Chou LJ(丑凌军)1; Chou LJ(丑凌军); Song HL(宋焕玲)
刊名Journal of Nanoparticle Research
出版日期2016
卷号18期号:3页码:66(1-17)
关键词Lanthanum Nanorods Platinum Selective hydrogenation Nanostructured catalysts
ISSN号1388-0764
通讯作者宋焕玲 ; 丑凌军
英文摘要

Rod-like and particle-like La2O2CO3 and La2O3 were obtained via morphology-preserved thermal transformation of the La(OH)3 precursors. La2O2CO3- and La2O3-supported Pt catalysts were prepared by impregnation method and tested in the liquid-phase crotonaldehyde hydrogenation reaction. The textural and physicochemical properties of the samples were studied by a series of techniques including XRD, TG-DSC, N2 adsorption–desorption, TEM and HRTEM, IR spectrum, H2-TPD, and H2-TPR. Even after 600 °C reduction, Pt particles of about 0.8–2.8 nm interplayed with support surface to form Pt-doped interface, thereby preventing the catalysts from migration and affording a high dispersion of platinum. The specific exposed crystal-facets and surface oxygen species depending on the shape of the support affected the preferential deposition of Pt species and the metal-support interaction. Thus, Pt catalysts performed different physicochemical properties and catalytic performance relying on the morphology and structure of the supports. During the cycle experiment, severe deactivation was observed for NP-supported catalysts with an increased selectivity due to the aggregation and growth of Pt particles. Meantime, the NR-supported catalysts retained relatively high reactivity as a consequence of the crystal-facet confinement of rod-shaped lanthanum supports.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the Western Light Program of Chinese Academy of Sciecces (2015);the National Science Foundation of China (21401204)
语种英语
WOS记录号WOS:000371295100001
源URL[http://210.77.64.217/handle/362003/19763]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Chou LJ(丑凌军); Song HL(宋焕玲)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Hou FJ,Zhao HH,Zhao J,et al. Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation[J]. Journal of Nanoparticle Research,2016,18(3):66(1-17).
APA Hou FJ.,Zhao HH.,Zhao J.,Yang J.,Yan L.,...&宋焕玲.(2016).Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation.Journal of Nanoparticle Research,18(3),66(1-17).
MLA Hou FJ,et al."Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation".Journal of Nanoparticle Research 18.3(2016):66(1-17).

入库方式: OAI收割

来源:兰州化学物理研究所

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