Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation
文献类型:期刊论文
作者 | Hou FJ(侯风君)1,2; Zhao HH(赵华华)1![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() |
刊名 | Journal of Nanoparticle Research
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出版日期 | 2016 |
卷号 | 18期号:3页码:66(1-17) |
关键词 | Lanthanum Nanorods Platinum Selective hydrogenation Nanostructured catalysts |
ISSN号 | 1388-0764 |
通讯作者 | 宋焕玲 ; 丑凌军 |
英文摘要 | Rod-like and particle-like La2O2CO3 and La2O3 were obtained via morphology-preserved thermal transformation of the La(OH)3 precursors. La2O2CO3- and La2O3-supported Pt catalysts were prepared by impregnation method and tested in the liquid-phase crotonaldehyde hydrogenation reaction. The textural and physicochemical properties of the samples were studied by a series of techniques including XRD, TG-DSC, N2 adsorption–desorption, TEM and HRTEM, IR spectrum, H2-TPD, and H2-TPR. Even after 600 °C reduction, Pt particles of about 0.8–2.8 nm interplayed with support surface to form Pt-doped interface, thereby preventing the catalysts from migration and affording a high dispersion of platinum. The specific exposed crystal-facets and surface oxygen species depending on the shape of the support affected the preferential deposition of Pt species and the metal-support interaction. Thus, Pt catalysts performed different physicochemical properties and catalytic performance relying on the morphology and structure of the supports. During the cycle experiment, severe deactivation was observed for NP-supported catalysts with an increased selectivity due to the aggregation and growth of Pt particles. Meantime, the NR-supported catalysts retained relatively high reactivity as a consequence of the crystal-facet confinement of rod-shaped lanthanum supports. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Western Light Program of Chinese Academy of Sciecces (2015);the National Science Foundation of China (21401204) |
语种 | 英语 |
WOS记录号 | WOS:000371295100001 |
源URL | [http://210.77.64.217/handle/362003/19763] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Chou LJ(丑凌军); Song HL(宋焕玲) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Hou FJ,Zhao HH,Zhao J,et al. Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation[J]. Journal of Nanoparticle Research,2016,18(3):66(1-17). |
APA | Hou FJ.,Zhao HH.,Zhao J.,Yang J.,Yan L.,...&宋焕玲.(2016).Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation.Journal of Nanoparticle Research,18(3),66(1-17). |
MLA | Hou FJ,et al."Morphological effect of lanthanum-based supports on the catalytic performance of Pt catalysts in crotonaldehyde hydrogenation".Journal of Nanoparticle Research 18.3(2016):66(1-17). |
入库方式: OAI收割
来源:兰州化学物理研究所
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