Anions Influence the Relaxation Dynamics of Mono-mu(3)-OH-Capped Triangular Dysprosium Aggregates
文献类型：期刊论文
| 作者 | Zhang,Li; Zhang,Peng; Zhao,Lang; Wu,Jianfeng; Guo,Mei; Tang,Jinkui |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:11页码:5571-5578 |
| 关键词 | SINGLE-MOLECULE MAGNETS COUPLING DY-3 TRIANGLES ION MAGNETS COORDINATION GEOMETRY COMPLEXES BEHAVIOR LIGAND ANISOTROPY EXCHANGE TRANSITION |
| 通讯作者 | tang,jk |
| 英文摘要 | a family of four dy-3 triangular circular helicates, namely, [dy-3(hl)(3)(mu(3)-oh)(ch3oh)(2)(h2o)(4)]cl-1.5(oh)(0.5).0.5h(2)o (1), [dy-3(hl)(3)(mu(3)-oh)(ch3oh)(3)(h2o)(2)cl]cl.ch3oh (2), [dy-3(hl)(3)(mu(3)-oh)(ch3oh)(3)(h2o)(2)(no3)](no3) (3), and [dy-3(hl)(3)(mu(3)-oh)(ch3oh)(4)(clo4)](clo4) (4), were assembled by the reaction of a new acylhydrazone ligand h3l [(3-hydroxy)-n'-((8-hydroxyquinolin-2-yl)methylene)picolinohydrazide] with different dysprosium(iii) salts. these compounds represent the first examples of mu-oacylhydrazone-bridged triangular dy3 smms reported to date. alternating-current magnetic susceptibility measurements revealed that compounds 1 and 2 show typical smm behavior with the occurrence of multiple relaxation processes, whereas frequency-dependent relaxation signals without chi peaks were observed in 3 and 4 under zero dc field. such distinct dynamic behaviors are attributed to the different sizes of the terminal coordination solvent/anions (h2o, cl, no3, and clo4 for 1-4, respectively) at the dy-3 site. here, similar deviations from the ideal monocapped square-antiprismatic (c-4v) geometry defined by shape software were observed around local dy centers in 1 and 2, whereas the situation was completely different in 3 and 4 as a result of the presence of relatively large anions in the limited space defined by three intercrossing rigid hydrazone ligands. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355638100064 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65071]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang,Li,Zhang,Peng,Zhao,Lang,et al. Anions Influence the Relaxation Dynamics of Mono-mu(3)-OH-Capped Triangular Dysprosium Aggregates[J]. inorganic chemistry,2015,54(11):5571-5578. |
| APA | Zhang,Li,Zhang,Peng,Zhao,Lang,Wu,Jianfeng,Guo,Mei,&Tang,Jinkui.(2015).Anions Influence the Relaxation Dynamics of Mono-mu(3)-OH-Capped Triangular Dysprosium Aggregates.inorganic chemistry,54(11),5571-5578. |
| MLA | Zhang,Li,et al."Anions Influence the Relaxation Dynamics of Mono-mu(3)-OH-Capped Triangular Dysprosium Aggregates".inorganic chemistry 54.11(2015):5571-5578. |
入库方式： OAI收割
来源：长春应用化学研究所
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