Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations
文献类型：期刊论文
| 作者 | Wu,Dai; Bai,Xiaojing; Tian,Hong-Rui; Yang,Weiting; Li,Zewen; Huang,Qing; Du,Shiyu; Sun,Zhong-Ming |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:17页码:8617-8624 |
| 关键词 | GENERALIZED GRADIENT APPROXIMATION METAL-ORGANIC FRAMEWORKS COORDINATION POLYMERS SPECTROSCOPIC PROPERTIES HYBRID MATERIALS COMPLEXES DIPHOSPHONATES TRANSFORMATION PHOSPHONATES PEROXIDE |
| 通讯作者 | yang,wt |
| 英文摘要 | wo uranyl carboxyphosphonates (h(2)dipy)[uo2)(3) (h2o)(2) (h2pptp)(2)]center dot 2h(2)o (dptp-u1) and (h(2)bbi)[(uo2)(4)(h2o)(2)(hdptp)(2)] (dptp-u2) [h6dptp = 2,5diphosphonoterephthalic acid, dipy = 4,4'-bipyridine, bbi = 1,1'-(1,4-butanediyobis(imidazole)] were synthesized under hydrothermal conditions. the carboxyphosphonate ligand was formed through the in situ oxidation of (2,5-dimethy1-1,4phenylene)diphosphonic acid mediated by uo22+. single-crystal x-ray diffraction analyses reveal that dptp-u1 possesses uranyl carboxyphosphonate layers that are separated by protonated dipy cations. whereas dptp-u2 is in a three-dimensional framework structure with channels filled by protonated bbi cations. the computational investigations give an insight into the nature of bonding interactions between uranium(vi) and carboxyphosphonate ligand. the spectroscopic properties were also studied. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000361085800053 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65073]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu,Dai,Bai,Xiaojing,Tian,Hong-Rui,et al. Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations[J]. inorganic chemistry,2015,54(17):8617-8624. |
| APA | Wu,Dai.,Bai,Xiaojing.,Tian,Hong-Rui.,Yang,Weiting.,Li,Zewen.,...&Sun,Zhong-Ming.(2015).Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations.inorganic chemistry,54(17),8617-8624. |
| MLA | Wu,Dai,et al."Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations".inorganic chemistry 54.17(2015):8617-8624. |
入库方式： OAI收割
来源：长春应用化学研究所
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