中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Three-dimensional Fe- and N-incorporated carbon structures as peroxidase mimics for fluorescence detection of hydrogen peroxide and glucose

文献类型:期刊论文

作者Zhang,Ruizhong; He,Shuijian; Zhang,Chunmei; Chen,Wei
刊名journal of materials chemistry b
出版日期2015
卷号3期号:20页码:4146-4154
关键词CUPRIC OXIDE NANOPARTICLES GRAPHENE QUANTUM DOTS IN-SITU GROWTH OXYGEN-REDUCTION COLORIMETRIC DETECTION GOLD NANOPARTICLES ENHANCED CHEMILUMINESCENCE ELECTROCHEMICAL DETECTION ALLOY NANOPARTICLES ARTIFICIAL ENZYMES
通讯作者chen,w
英文摘要in this study, a simple and one-pot pyrolysis strategy is developed for the mass production of fe, n-incorporated carbon nanotubes in situ grown on 3d porous carbon foam (denoted as fe-phen-cfs), which provides highly active fe-n and doped-n species, and a large surface area with exposed active sites. the obtained composite exhibits intrinsic peroxidase-like catalytic activities. with the fe-phen-cfs as the catalyst, the peroxidase substrate of terephthalic acid (ta) can be oxidized to the fluorescent product of hydroxyterephthalate (hta) by h2o2, which provides a unique strategy for fluorescence detection of h2o2. with such a process, as low as 68 nm h2o2 could be detected with a linear range from 0.1 to 100 mu m. meanwhile, by integrating glucose oxidase on the fe-phen-cfs composite, sensitive detection of glucose is also achieved with a linear range from 0.5 to 200 mm and a limit of detection of 0.19 mm. most importantly, such a novel ta/fe-phen-cfs system can be successfully applied to glucose determination in real human serum samples. the unique nature and 3d structure of the fe-phen-cfs composite makes it promising for the fabrication of low-cost, high-performance biosensors.
收录类别SCI
语种英语
公开日期2016-05-31
源URL[http://ir.ciac.jl.cn/handle/322003/65079]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhang,Ruizhong,He,Shuijian,Zhang,Chunmei,et al. Three-dimensional Fe- and N-incorporated carbon structures as peroxidase mimics for fluorescence detection of hydrogen peroxide and glucose[J]. journal of materials chemistry b,2015,3(20):4146-4154.
APA Zhang,Ruizhong,He,Shuijian,Zhang,Chunmei,&Chen,Wei.(2015).Three-dimensional Fe- and N-incorporated carbon structures as peroxidase mimics for fluorescence detection of hydrogen peroxide and glucose.journal of materials chemistry b,3(20),4146-4154.
MLA Zhang,Ruizhong,et al."Three-dimensional Fe- and N-incorporated carbon structures as peroxidase mimics for fluorescence detection of hydrogen peroxide and glucose".journal of materials chemistry b 3.20(2015):4146-4154.

入库方式: OAI收割

来源:长春应用化学研究所

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