Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers
文献类型：期刊论文
| 作者 | Li,Zong-Jun; Li,Shu-Hui; Sun,Tao; Hou,Hui-Lei; Gao,Xiang |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 80期号:7页码:3566-3571 |
| 关键词 | SOLAR-CELLS FULLERENE CHEMISTRY AROMATIC NITRILES RADICAL REACTIONS DERIVATIVES FUNCTIONALIZATION ELECTROSYNTHESIS FULLEROOXAZOLES GENERATION HYDROXIDE |
| 通讯作者 | gao,x |
| 英文摘要 | upon reduction, singly bonded 1,2,4,15-c-60 dimers with an oxazoline or imidazoline heterocycle dissociate into monoanionic 1,2,4-c-60 intermediates, which surprisingly leads to the formation of 1,2,3,16-c-60 rather than 1,2,4,15-c-60 adducts of the original configuration by further benzylation, even though the analogue of dibenzylated c-60 oxazoline with a 1,2,4,15-configuration is stable and has been obtained. these results are corroborated by computational calculations, which rationalize the reaction and clarify the structure of the 1,2,3,16-c-60 adducts, providing new insights into the intrinsic reactivity of singly bonded c-60 dimers. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65089]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,et al. Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers[J]. journal of organic chemistry,2015,80(7):3566-3571. |
| APA | Li,Zong-Jun,Li,Shu-Hui,Sun,Tao,Hou,Hui-Lei,&Gao,Xiang.(2015).Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers.journal of organic chemistry,80(7),3566-3571. |
| MLA | Li,Zong-Jun,et al."Reductive Benzylation of Singly Bonded 1,2,4,15-C-60 Dimers with an Oxazoline or Imidazoline Heterocycle: Unexpected Formation of 1,2,3,16-C-60 Adducts and Insights into the Reactivity of Singly Bonded C-60 Dimers".journal of organic chemistry 80.7(2015):3566-3571. |
入库方式： OAI收割
来源：长春应用化学研究所
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