Preparation of a C-70 Bis-heterocyclic Derivative with High Chemio- and Regioselectivity
文献类型:期刊论文
| 作者 | Hou,Hui-Lei; Li,Zong-Jun; Sun,Tao; Gao,Xiang |
| 刊名 | journal of organic chemistry
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| 出版日期 | 2015 |
| 卷号 | 80期号:10页码:5315-5319 |
| 关键词 | RETRO-CYCLOADDITION REACTION MANGANESE(III) ACETATE FULLERENE DERIVATIVES FERRIC PERCHLORATE MEDIATED SYNTHESIS AROMATIC NITRILES RADICAL REACTIONS SOLAR-CELLS C-60 FUNCTIONALIZATION |
| 通讯作者 | gao,x |
| 英文摘要 | c-70 bis-heterocyclic derivative (1) bearing one oxazoline ring and one imidazoline ring with the 2 o'clock configuration is obtained with high chemio- and regioselectivity via the reaction of c-70 with hydroxide and benzonitrile quenched with i-2. further study with benzylation experiment and theoretical calculations indicate that the oxazoline ring is the one first formed on the c-70 cage, while the imidazoline ring is the one formed after the addition of i-2 via a radical coupling reaction mechanism. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354908500051 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65090] ![]() |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hou,Hui-Lei,Li,Zong-Jun,Sun,Tao,et al. Preparation of a C-70 Bis-heterocyclic Derivative with High Chemio- and Regioselectivity[J]. journal of organic chemistry,2015,80(10):5315-5319. |
| APA | Hou,Hui-Lei,Li,Zong-Jun,Sun,Tao,&Gao,Xiang.(2015).Preparation of a C-70 Bis-heterocyclic Derivative with High Chemio- and Regioselectivity.journal of organic chemistry,80(10),5315-5319. |
| MLA | Hou,Hui-Lei,et al."Preparation of a C-70 Bis-heterocyclic Derivative with High Chemio- and Regioselectivity".journal of organic chemistry 80.10(2015):5315-5319. |
入库方式: OAI收割
来源:长春应用化学研究所
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