中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Two-step ion-exchange synthetic strategy for obtaining monodisperse NaYF4:Ln(3+) nanostructures with multicolor luminescence properties

文献类型:期刊论文

作者Shao,Baiqi; Zhao,Qi; Lv,Wenzhen; Jiao,Mengmeng; Lu,Wei; You,Hongpeng
刊名journal of materials chemistry c
出版日期2015
卷号3期号:5页码:1091-1098
关键词UP-CONVERSION LUMINESCENCE NANOCRYSTALS LANTHANIDE NANOPARTICLES PERFORMANCE PHASE WATER
通讯作者shao,bq
英文摘要monodisperse beta-nayf4:ln(3+) (ln = eu, tb, yb/er, or yb/tm) nanocrystals with multiform novel morphologies have been synthesized for the first time by a novel two-step ion-exchange route expressed as y-2(oh)(5)no3 center dot nh(2)o (lyh) -> y(oh)(x)f3-x -> beta-nayf4. in step i (lyh -> y(oh)(x)f3-x), the y(oh)(x)f3-x is fabricated using a one-pot method from the starting point of a unit layer at low temperature through a novel style of ion-exchange from lyh based on the special crystal structural similarity between the lyh unit layer and the y(oh)(x)f3-x {0001} plane. of particular interest is that the ion-exchange process in step i can be completed within the initial few minutes, and the unique two-dimensional layered structure of lyh greatly favors the ion-exchange reaction by exfoliating into atomically thick monolayers. meanwhile, the identical structural framework between y(oh)(x)f3- x and beta-nayf4 ensures the in situ ion-exchange reaction in step ii. the composition of the intermediate precursor y(oh)(x)f3-x can be tuned in a wide range, which gives the synthetic parameters high maneuverability and greatly simplifies the experimental variables. in addition, the luminescence properties showed that the as-prepared beta-nayf4:ln(3+) nanocrystals exhibited strong characteristic multicolor emissions through upconversion and downconversion.
收录类别SCI
语种英语
公开日期2016-05-31
源URL[http://ir.ciac.jl.cn/handle/322003/65093]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Shao,Baiqi,Zhao,Qi,Lv,Wenzhen,et al. Two-step ion-exchange synthetic strategy for obtaining monodisperse NaYF4:Ln(3+) nanostructures with multicolor luminescence properties[J]. journal of materials chemistry c,2015,3(5):1091-1098.
APA Shao,Baiqi,Zhao,Qi,Lv,Wenzhen,Jiao,Mengmeng,Lu,Wei,&You,Hongpeng.(2015).Two-step ion-exchange synthetic strategy for obtaining monodisperse NaYF4:Ln(3+) nanostructures with multicolor luminescence properties.journal of materials chemistry c,3(5),1091-1098.
MLA Shao,Baiqi,et al."Two-step ion-exchange synthetic strategy for obtaining monodisperse NaYF4:Ln(3+) nanostructures with multicolor luminescence properties".journal of materials chemistry c 3.5(2015):1091-1098.

入库方式: OAI收割

来源:长春应用化学研究所

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