Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets
文献类型：期刊论文
| 作者 | Lu,Yizhong; Jiang,Yuanyuan; Wu,Haibin; Chen,Wei |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2015 |
| 卷号 | 156期号:7页码:267-273 |
| 关键词 | INTERVALENCE TRANSFER RUTHENIUM NANOPARTICLES STATE DELOCALIZATION COMPLEXES IONS XPS TRANSITION CHEMISTRY SURFACES |
| 通讯作者 | chen,w |
| 英文摘要 | graphene oxide (go) nanosheets functionalized with ferrocenyl moieties (go-fc) were fabricated through strong covalent c-c bonds. the resulting hybrid showed efficient electronic communication between ferrocene centers due to the strong electron delocalization facilitated by the large pi-pi conjugated structure of graphene sheets. the obtained hybrid exhibited two pairs of voltammetric peaks with a large potential spacing of 0.515v and a broad absorption peak in the near-infrared range (similar to 1428 nm) at mixed valence. the electrochemical and near ir spectroscopic features suggested a class ii/iii behavior of the intervalence charge transfer. this work indicates clearly that strong electronic coupling between ferrocene centers can be easily realized across graphene nanosheets with sp(2)-hybridized carbon. (c) 2015 elsevier ltd. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350444600034 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65129]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu,Yizhong,Jiang,Yuanyuan,Wu,Haibin,et al. Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets[J]. electrochimica acta,2015,156(7):267-273. |
| APA | Lu,Yizhong,Jiang,Yuanyuan,Wu,Haibin,&Chen,Wei.(2015).Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets.electrochimica acta,156(7),267-273. |
| MLA | Lu,Yizhong,et al."Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets".electrochimica acta 156.7(2015):267-273. |
入库方式： OAI收割
来源：长春应用化学研究所
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