Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue
文献类型：期刊论文
| 作者 | Lin,Shuang-Yan; Wang,Chao; Zhao,Lang; Wu,Jianfeng; Tang,Jinkui |
| 刊名 | dalton transactions
 |
| 出版日期 | 2015 |
| 卷号 | 44期号:1页码:223-229 |
| 关键词 | MOLECULE-MAGNET FERROELECTRIC PROPERTIES LOW-SYMMETRY RELAXATION LIGAND SPIN ANISOTROPY (1R 2 MAGNETIZATION 2R)-1 6-DIFORMYL-4-METHYLPHENOL 2-DIAMINOCYCLOHEXANE |
| 通讯作者 | tang,jk |
| 英文摘要 | three pairs of homochiral mononuclear lanthanide complexes, with the general formula [lnh(4)l(rrrrrr/ssssss)(scn)(2)](scn)(2)center dot xch(3)oh center dot yh(2)o(ln = dy (r/s-dy-1), ho (r/s-ho-1) and er (r/s-er-1)), have been obtained via self-assembly between chiral macrocyclic ligands and the respective thiocyanates, all of which show a saddle-type conformation with seven-coordinated metal ions. magnetic measurements revealed that the dy complex shows field-induced single-ion magnet behaviour, which is rarely reported in a seven-coordinated lanthanide-based sim encapsulated in a macrocyclic ligand. the absolute configuration of all enantiomers was determined by single crystal x-ray crystallography and confirmed by electronic cd and vcd spectra. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65149]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin,Shuang-Yan,Wang,Chao,Zhao,Lang,et al. Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue[J]. dalton transactions,2015,44(1):223-229. |
| APA | Lin,Shuang-Yan,Wang,Chao,Zhao,Lang,Wu,Jianfeng,&Tang,Jinkui.(2015).Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue.dalton transactions,44(1),223-229. |
| MLA | Lin,Shuang-Yan,et al."Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue".dalton transactions 44.1(2015):223-229. |
入库方式： OAI收割
来源：长春应用化学研究所
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