Assembly of three coordination polymers based on a sulfonic-carboxylic ligand showing high proton conductivity
文献类型：期刊论文
| 作者 | Zhao,Shu-Na; Song,Xue-Zhi; Zhu,Min; Meng,Xing; Wu,Lan-Lan; Song,Shu-Yan; Wang,Cheng; Zhang,Hong-Jie |
| 刊名 | dalton transactions
 |
| 出版日期 | 2015 |
| 卷号 | 44期号:3页码:948-954 |
| 关键词 | METAL-ORGANIC FRAMEWORK ION CONDUCTIVITY FUEL-CELLS ACID MOF LUMINESCENCE CONDUCTORS DIVERSITY MOLECULES TRANSPORT |
| 通讯作者 | song,sy |
| 英文摘要 | three new coordination polymers (cps)/metal-organic frameworks (mofs) with different structures have been synthesized using 4,8-disulfonyl-2,6-naphthalenedicarboxylic acid (h4l) and metal ions, cu2+, ca2+ and cd2+. the cu compound features a one-dimensional chain structure, further extending into a 2d layer network through h-bond interactions. both the ca and cd compounds show 3d frameworks with (4,4)-connected pts-type topology and (3,6)-connected bct-type topology, respectively. these cps/mofs all exhibit proton conduction behavior, especially for the cu compound with a proton conductivity of 3.46 x 10(-3) s cm(-1) at 368 k and 95% relative humidity (rh). additionally, the activation energy (e-a) has also been investigated to deeply understand the proton-conduction mechanism. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65150]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao,Shu-Na,Song,Xue-Zhi,Zhu,Min,et al. Assembly of three coordination polymers based on a sulfonic-carboxylic ligand showing high proton conductivity[J]. dalton transactions,2015,44(3):948-954. |
| APA | Zhao,Shu-Na.,Song,Xue-Zhi.,Zhu,Min.,Meng,Xing.,Wu,Lan-Lan.,...&Zhang,Hong-Jie.(2015).Assembly of three coordination polymers based on a sulfonic-carboxylic ligand showing high proton conductivity.dalton transactions,44(3),948-954. |
| MLA | Zhao,Shu-Na,et al."Assembly of three coordination polymers based on a sulfonic-carboxylic ligand showing high proton conductivity".dalton transactions 44.3(2015):948-954. |
入库方式： OAI收割
来源：长春应用化学研究所
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