Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes
文献类型：期刊论文
| 作者 | Mou,Zehuai; Xie,Hongyan; Wang,Meiyan; Liu,Na; Yao,Changguang; Li,Lei; Liu,Jingyao; Li,Shihui; Cui,Dongmei |
| 刊名 | organometallics
 |
| 出版日期 | 2015 |
| 卷号 | 34期号:16页码:3944-3949 |
| 关键词 | N-HETEROCYCLIC CARBENES H BOND HYDROGEN-ATOMS ZN-H COMPLEXES KETONES DIAMINE LIGAND FUNCTIONALIZATION HETEROCUMULENES |
| 通讯作者 | cui,dm |
| 英文摘要 | treatment of heteroscorpionate zinc benzyloxy complex lznobn (1, l = ((me)pz)(2)cp(ph)(2)nph, (me)pz = 3,5-dimethylpyrazolyl) with phenylsilane (phsih3) gave a zinc hydride complex lznh (2) containing a rare terminal hydride fragment. x-ray diffraction analysis and the dft calculation confirm the zwitterionic structure of complex 2. the stoichiometric reaction of 2 with cs2 readily afforded a dithioformate complex lznsch(s) (3) of the c=s insertion into the zn-h product. moreover, complex 2 was an efficient catalyst for the hydrosilylation reaction of a series of silanes and aldehydes under mild conditions, featuring excellent functional group tolerance. the preliminary mechanistic study revealed that both zinc benzyloxy complex 1 and zinc hydride complex 2 were involved in the hydrosilylation process as the reaction intermediates. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000360322500005 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65181]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Mou,Zehuai,Xie,Hongyan,Wang,Meiyan,et al. Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes[J]. organometallics,2015,34(16):3944-3949. |
| APA | Mou,Zehuai.,Xie,Hongyan.,Wang,Meiyan.,Liu,Na.,Yao,Changguang.,...&Cui,Dongmei.(2015).Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes.organometallics,34(16),3944-3949. |
| MLA | Mou,Zehuai,et al."Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes".organometallics 34.16(2015):3944-3949. |
入库方式： OAI收割
来源：长春应用化学研究所
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