Constructing calixarene-supported high nuclearity Co-27, Co-28 and Ni18Na6 clusters with triazoles as co-bridges
文献类型：期刊论文
| 作者 | Wang,Shentang; Bi,Yanfeng; Liao,Wuping |
| 刊名 | crystengcomm
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:14页码:2896-2902 |
| 关键词 | METAL-ORGANIC SUPERCONTAINERS COORDINATION CAGES TRANSITION-METAL GUEST-BINDING THIACALIXARENE FRAMEWORK NI POLYHEDRA ZN |
| 通讯作者 | wang,st |
| 英文摘要 | three nanosized flying saucer-like cobalt compounds, [co-28(tc(4)a)(6)(3-sh-trz)(8)(di-s-trz)(4)(so4)cl-10(oh)(4)(ch3oh)(4)(h2o)(6)] (ciac-210), [co-27(tc(4)a)(6)(3-sh-trz)(8)(di-s-trz)(4)(co3)(0.25)(so3)(0.75)cl-10(oh)(2)(ch3oh)(2)(h2o)(4)] (ciac-1211) and [co-28(tc(4)a)(6)(trz)(16)(co3)cl-11(oh)(3)(ch3oh)(2)(h2o)(6)] (ciac-212), and one ring-like mixed nina compound, [ni18na6(tc(4)a)(6)(3-s-trz)(6)cl-6(h2o)(6)] (ciac-213), were obtained by solvothermal reactions of the metal salts, p-tert-butyltetrathiacalix[4]arene (h(4)tc(4)a) and 1h-1,2,4-triazole-3-thiol (1h-3-sh-trz)/1h-1,2,4-triazole-3-carboxylic acid (1h-3-cooh-trz). all these four compounds are feathered with some shuttlecock-like secondary building units (sbus) which are constructed by four metal atoms capped by a calixarene molecule. in ciac-210, -211 and -213, the m4-tc4a sbus are bridged together by 3-sh-trz and its dimer, forming high nuclearity clusters, while in ciac-212, the sbus are bridged by 1h-1,2,4-triazole (trz). it is found that not only the kind of metal and the molar ratio of the reactants play important roles in the formation of the clusters, but also the mixed solvents and their ratio affect the final structures. magnetic measurements suggested that the metal centers exhibit antiferromagnetic interactions for all these four compounds. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351764600014 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/65205]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang,Shentang,Bi,Yanfeng,Liao,Wuping. Constructing calixarene-supported high nuclearity Co-27, Co-28 and Ni18Na6 clusters with triazoles as co-bridges[J]. crystengcomm,2015,17(14):2896-2902. |
| APA | Wang,Shentang,Bi,Yanfeng,&Liao,Wuping.(2015).Constructing calixarene-supported high nuclearity Co-27, Co-28 and Ni18Na6 clusters with triazoles as co-bridges.crystengcomm,17(14),2896-2902. |
| MLA | Wang,Shentang,et al."Constructing calixarene-supported high nuclearity Co-27, Co-28 and Ni18Na6 clusters with triazoles as co-bridges".crystengcomm 17.14(2015):2896-2902. |
入库方式： OAI收割
来源：长春应用化学研究所
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