Highly thermostable lanthanide metal-organic frameworks exhibiting unique selectivity for nitro explosives
文献类型：期刊论文
| 作者 | Zhao,Shu-Na; Song,Xue-Zhi; Zhu,Min; Meng,Xing; Wu,Lan-Lan; Song,Shu-Yan; Wang,Cheng; Zhang,Hong-Jie |
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:1页码:93-98 |
| 关键词 | NITROAROMATIC EXPLOSIVES COORDINATION POLYMERS LUMINESCENCE PROPERTIES TUNABLE LUMINESCENCE SENSORS MOLECULES FLUORESCENCE EUROPIUM CRYSTALS SITES |
| 通讯作者 | song,sy |
| 英文摘要 | three isostructural 3d metal-organic frameworks [ln(l)(1.5)(def)](n) (ln = gd (1), eu (2), tb (3), h2l = 9,9-diethylfluorene-2,7-dicarboxylic acid) have been solvothermally synthesized and structurally characterized by single-crystal x-ray diffraction. the main framework of compounds 1-3 show high thermal stability to 400 degrees c but with a distortion or shrinking of the crystal lattice between 200 degrees c and 250 degrees c. the high red emission intensity and the microporous instinct of the solvent-free [eu(l)(1.5)](n) (2a) indicate that it can be potentially used as luminescent sensor. it was then applied in the detection of organic solvent molecules. notably, it exhibits high sensitivity for 2,4,6-trinitrophenol (tnp) with k-sv constant 6.24 x 10(4) m-1 through luminescence quenching experiments. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67808]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao,Shu-Na,Song,Xue-Zhi,Zhu,Min,et al. Highly thermostable lanthanide metal-organic frameworks exhibiting unique selectivity for nitro explosives[J]. rsc advances,2015,5(1):93-98. |
| APA | Zhao,Shu-Na.,Song,Xue-Zhi.,Zhu,Min.,Meng,Xing.,Wu,Lan-Lan.,...&Zhang,Hong-Jie.(2015).Highly thermostable lanthanide metal-organic frameworks exhibiting unique selectivity for nitro explosives.rsc advances,5(1),93-98. |
| MLA | Zhao,Shu-Na,et al."Highly thermostable lanthanide metal-organic frameworks exhibiting unique selectivity for nitro explosives".rsc advances 5.1(2015):93-98. |
入库方式： OAI收割
来源：长春应用化学研究所
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