Enzymatic degradation and porous morphology of poly(L-lactide) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends
文献类型:期刊论文
作者 | Ju,Dandan; Han,Lijing; Bian,Junjia; Guo,Ziqi; Li,Fan; Chen,Shan; Dong,Lisong |
刊名 | rsc advances
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出版日期 | 2015 |
卷号 | 5期号:7页码:5474-5483 |
关键词 | ALIPHATIC POLYESTERS BIODEGRADABLE POLYESTERS HYDROLYSIS FILMS SCAFFOLDS POLYHYDROXYALKANOATES CRYSTALLIZATION COPOLYMERS ALKALINE LACTIDE |
通讯作者 | han,lj |
英文摘要 | fully biodegradable polymer blends based on biosourced polymers, namely poly(l-lactide) (plla) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) (p(3hb-co-4hb)) are prepared by melt compounding. the enzymatic degradation and porous morphology of plla/p(3hb-co-4hb) blends are investigated in detail. the lipase from pseudomonas mendocina reveals preferred enzymatic degradation of p(3hb-co-4hb) but insignificant attack to plla in the blends. at the same time, proteinase k can degrade plla, but cannot degrade p(3hb-co-4hb). on account of the surface erosion mechanisms, the enzymatic degradation rates of both the p(3hb-co-4hb) and plla in the blends are improved because of the presence of the other component to increase the specific surface area. the results of the h-1 nmr and gpc indicate that there is no more intermediate products formed during the enzymatic degradation of the plla and p(3hb-co-4hb). due to the specificity of the degradation enzymes, selective enzymatic degradation is adopted to degrade and remove one component from the blends, and various porous morphologies are acquired. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-31 |
源URL | [http://ir.ciac.jl.cn/handle/322003/67815] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ju,Dandan,Han,Lijing,Bian,Junjia,et al. Enzymatic degradation and porous morphology of poly(L-lactide) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends[J]. rsc advances,2015,5(7):5474-5483. |
APA | Ju,Dandan.,Han,Lijing.,Bian,Junjia.,Guo,Ziqi.,Li,Fan.,...&Dong,Lisong.(2015).Enzymatic degradation and porous morphology of poly(L-lactide) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends.rsc advances,5(7),5474-5483. |
MLA | Ju,Dandan,et al."Enzymatic degradation and porous morphology of poly(L-lactide) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) blends".rsc advances 5.7(2015):5474-5483. |
入库方式: OAI收割
来源:长春应用化学研究所
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