Impact of particle surface chemistry on the structure and rheological properties of graphene-based particle/polydimethylsiloxane composites
文献类型：期刊论文
| 作者 | Niu,Ran; Gong,Jiang; Xu,Donghua; Tang,Tao; Sun,Zhao-Yan |
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:44页码:34885-34893 |
| 关键词 | CARBON NANOTUBES AQUEOUS DISPERSIONS PI-INTERACTIONS GRAPHITE OXIDE NANOCOMPOSITES FLOW SUSPENSIONS NANOSHEETS SHEETS POLYDIMETHYLSILOXANE |
| 通讯作者 | xu,dh |
| 英文摘要 | the structure and rheological properties of graphene-based particle (gp-x)/polydimethylsiloxane (pdms) composites are investigated as the surface oxygen content of graphene-based particle is varied, i.e., from 6.6% (gp-1) to 15.3% (gp-2), 25.5% (gp-3) and 43.1% (gp-4). interestingly, the dispersion state of graphene-based particles in pdms does not change monotonically with increasing surface oxygen content. the size of layered stacks and aggregates first decreases from gp-1 to gp-3 and then increases from gp-3 to gp-4 with increasing surface oxygen content. the larger size of layered stacks and aggregates in gp-1 and gp-4 suspensions results from strong inter-particle p-p and hydrogen bonding interactions. under weak shear, gp-1 and gp-4 form larger aggregates in pdms, which align along the vorticity direction, inducing negative normal stress differences (delta n) in the composites. however, gp-2 and gp-3 do not further aggregate under weak shear and the delta n is almost zero. it is further inferred that the strong inter-particle attractive interaction leads to the vorticity alignment of aggregates under weak shear. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67838]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Niu,Ran,Gong,Jiang,Xu,Donghua,et al. Impact of particle surface chemistry on the structure and rheological properties of graphene-based particle/polydimethylsiloxane composites[J]. rsc advances,2015,5(44):34885-34893. |
| APA | Niu,Ran,Gong,Jiang,Xu,Donghua,Tang,Tao,&Sun,Zhao-Yan.(2015).Impact of particle surface chemistry on the structure and rheological properties of graphene-based particle/polydimethylsiloxane composites.rsc advances,5(44),34885-34893. |
| MLA | Niu,Ran,et al."Impact of particle surface chemistry on the structure and rheological properties of graphene-based particle/polydimethylsiloxane composites".rsc advances 5.44(2015):34885-34893. |
入库方式： OAI收割
来源：长春应用化学研究所
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