Utilization of carbon dioxide to build a basic block for polymeric materials: an isocyanate-free route to synthesize a soluble oligourea
文献类型：期刊论文
| 作者 | Ying,Zhong; Zhao,Lijun; Zhang,Chao; Yu,Yancun; Liu,Tong; Cheng,Haiyang; Zhao,Fengyu |
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:52页码:42095-42100 |
| 关键词 | N-PHOSPHONIUM SALTS POLYUREA MICROCAPSULES MECHANICAL-PROPERTIES CORROSION-RESISTANCE CYCLIC CARBONATES MILD CONDITIONS DIAMINES DISULFIDE CHLORIDES PYRIDINES |
| 通讯作者 | zhao,fy |
| 英文摘要 | a water soluble oligourea was synthesized by an isocyanate-free route from carbon dioxide and diamine in the absence of any organic solvents or additives. the chemical structure of the product was confirmed by ftir and c-13 nmr analysis, and the average molecular weight was estimated with maldi-tof ms. the weight average molecular weight of the obtained oligourea is about 2210 da reacting under 180 degrees c and 11 mpa for 12 h. moreover, the prepared oligourea has a moderate thermo-stability, it has an initial decomposition temperature at similar to 220 degrees c and a melting temperature of 110 degrees c, as confirmed by tga and dsc. as a soluble oligomer, it could be used as a building block to synthesize co2-based polymeric materials due to it possessing a chemically active amino end group. for example, foaming plastics, greases, spun fibers and high strength polymer materials may be fabricated by reaction of the oligomer with a chain extender like a diisocyanate, diester or diacid. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67846]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ying,Zhong,Zhao,Lijun,Zhang,Chao,et al. Utilization of carbon dioxide to build a basic block for polymeric materials: an isocyanate-free route to synthesize a soluble oligourea[J]. rsc advances,2015,5(52):42095-42100. |
| APA | Ying,Zhong.,Zhao,Lijun.,Zhang,Chao.,Yu,Yancun.,Liu,Tong.,...&Zhao,Fengyu.(2015).Utilization of carbon dioxide to build a basic block for polymeric materials: an isocyanate-free route to synthesize a soluble oligourea.rsc advances,5(52),42095-42100. |
| MLA | Ying,Zhong,et al."Utilization of carbon dioxide to build a basic block for polymeric materials: an isocyanate-free route to synthesize a soluble oligourea".rsc advances 5.52(2015):42095-42100. |
入库方式： OAI收割
来源：长春应用化学研究所
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