Palladacycles derived from arylphosphinamides for mild Suzuki-Miyaura cross-couplings
文献类型：期刊论文
| 作者 | Wu,Guo-Jie; Han,Fu-She; Zhao,Yu-Long |
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:85页码:69776-69781 |
| 关键词 | ORTHO-SUBSTITUTED BIARYLS HINDERED ARYL CHLORIDES ROOM-TEMPERATURE BORONIC ACIDS ARYLBORONIC ACIDS EFFICIENT SYNTHESIS PHENOL DERIVATIVES CATALYST SYSTEM C-N PALLADIUM |
| 通讯作者 | han,fs |
| 英文摘要 | we present a type of palladacyclic complexes derived from arylphosphinamides which can be used as efficient and versatile precatalysts for mild suzuki-miyaura cross-coupling. with the presence of 1.0 mol% of palladacycles, a wide variety of aryl bromides and boronic acids could be coupled very efficiently at ambient temperature and under air atmosphere without the need of external supporting ligands. moreover, the mild conditions also allow for smooth coupling of electron-deficient, i.e., the less stable aryl triflates. in addition to the highly catalytic activity, the palladacyclic complexes can be very easily prepared through a two-step procedure from the readily affordable diphenyl-phosphinic chloride and exhibit excellent stability toward air and moisture. due to these prominent properties, the new palladacycles would find practical use in suzuki-miyaura couplings. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67852]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu,Guo-Jie,Han,Fu-She,Zhao,Yu-Long. Palladacycles derived from arylphosphinamides for mild Suzuki-Miyaura cross-couplings[J]. rsc advances,2015,5(85):69776-69781. |
| APA | Wu,Guo-Jie,Han,Fu-She,&Zhao,Yu-Long.(2015).Palladacycles derived from arylphosphinamides for mild Suzuki-Miyaura cross-couplings.rsc advances,5(85),69776-69781. |
| MLA | Wu,Guo-Jie,et al."Palladacycles derived from arylphosphinamides for mild Suzuki-Miyaura cross-couplings".rsc advances 5.85(2015):69776-69781. |
入库方式： OAI收割
来源：长春应用化学研究所
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