Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes
文献类型：期刊论文
| 作者 | Yao,Changguang; Xie,Hongyan; Cui,Dongmei |
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:113页码:93507-93512 |
| 关键词 | H BOND ACTIVATION ISOPRENE POLYMERIZATION CATIONIC POLYMERIZATION ALKYL COMPLEXES COPOLYMERIZATION CATALYSIS POLY(2-PHENYLBUTADIENE) YTTRIUM BEARING |
| 通讯作者 | cui,dm |
| 英文摘要 | a series of amidino n-heterocyclic carbene ligand supported rare-earth metal bis(alkyl) complexes (2,6-(r2c6h3n)-c-1=(crnch2ch2)-n-2(nchchn(c6h2me3-2,4,6)c))ln(ch2sime3)(2) [r-1 = pr-i, r-2 = ph, ln = lu (1a); r-1 = pr-i, r-2 = ph, ln = sc (1b); r-1 = ipr, r-2 = bu-t, ln = lu (2a); r-1 = me, r-2 = ph, ln = lu (3a)] were synthesized and characterized by nmr spectroscopy. on activation with [(ph3c)][(b(c6f5)(4))], complexes 1a, 2a and 3a exhibited high activities and high 3,4-selectivities (96.9%) for the polymerization of 2-phenyl-1,3-butadiene in a living mode to afford new plastic polydienes with high glass-transition temperatures (44.3-56.1 degrees c). the 3,4-selectivity decreased with increasing the polymerization temperature (25-60 degrees c), but increased with polarity of polymerization solvent in the order of chlorobenzene > toluene > cyclohexane. in contrast, complex 1b was almost inert for the polymerization of 2-phenyl-1,3-butadiene owing to its steric bulkiness. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67865]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yao,Changguang,Xie,Hongyan,Cui,Dongmei. Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes[J]. rsc advances,2015,5(113):93507-93512. |
| APA | Yao,Changguang,Xie,Hongyan,&Cui,Dongmei.(2015).Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes.rsc advances,5(113),93507-93512. |
| MLA | Yao,Changguang,et al."Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes".rsc advances 5.113(2015):93507-93512. |
入库方式： OAI收割
来源：长春应用化学研究所
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