An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester
文献类型：期刊论文
| 作者 | Liu,Na; Yao,Changguang; Lin,Fei; Liu,Bo; Cui,Dongmei |
| 刊名 | polymer
 |
| 出版日期 | 2015 |
| 卷号 | 80期号:47页码:104-108 |
| 关键词 | RING-OPENING POLYMERIZATION ALKALINE-EARTH CATALYSTS POLY(LACTIC ACID) INTERMOLECULAR HYDROPHOSPHINATION BIODEGRADABLE POLYESTERS IMMORTAL POLYMERIZATION LACTIDE POLYMERIZATION COMPLEXES CALCIUM DEGRADATION |
| 通讯作者 | cui,dm |
| 英文摘要 | an intensification and integration process of preparing highly thermal stable polylactide was reported. calcium complex 1 [lcan(sime3)(2)](2) (l = 2,5-bis-((pyrrolidin-1-yl)methene)-1h-pyrrole) was employed to synthesize the alcoholic chain-transfer agent and catalyze the immortal ring-opening polymerization of l-lactide in one pot. h-1 nmr spectrum and maldi-tof mass spectrum analyses indicated that the polymer was end-capped by phosphate ester and hydroxyl groups. the resultant phosphate ester capped polylactide exhibited a t-onset of 57 degrees c higher than that ended with benzyloxy group, since the unzip degradation of plla initiated by back-biting was inhibited during the heating process. (c) 2015 elsevier ltd. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-31 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/67898]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu,Na,Yao,Changguang,Lin,Fei,et al. An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester[J]. polymer,2015,80(47):104-108. |
| APA | Liu,Na,Yao,Changguang,Lin,Fei,Liu,Bo,&Cui,Dongmei.(2015).An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester.polymer,80(47),104-108. |
| MLA | Liu,Na,et al."An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester".polymer 80.47(2015):104-108. |
入库方式： OAI收割
来源：长春应用化学研究所
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