Photorefractive performance of a novel multifunctional inorganic-organic hybridized nanocomposite sensitized by CdS nanoparticles
文献类型：期刊论文
| 作者 | Ding Liyun ; Jiang DeSheng ; Huang Jun ; Erdan Gu ; Liu LR(刘立人) ; Chai ZF(柴志方) ; Liu DA(刘德安) |
| 刊名 | j. phys. chem. c
 |
| 出版日期 | 2008 |
| 卷号 | 112期号:27页码:10266 |
| 关键词 | Carbazolyl CdS nano-particles Cou pling reactions Film-forming materials Glass transition temperature Tg Inorganic-organic Molar ratios Photo-refractive |
| ISSN号 | 1932-7447 |
| 中文摘要 | a novel multifunctional inorganic-organic photorefractive (pr) poly(n-vinyl)-3-[p-nitrophenylazolcarbazolyl-cds nanocomposites with different molar ratios of us to poly(n-vinyl)-3-[p-nitrophenylazo]carbazolyl (pvnpak) were synthesized via a postazo-coupling reaction and chemically hybridized approach, respectively. the nanocomposites are highly soluble and could be obtained as film-forming materials with appreciably high molecular weights and low glass transition temperature (t,) due to the flexible spacers. the pvnpak matrix possesses a highest-occupied molecular orbital value of about -5.36 ev determined from cyclic voltammetry. second harmonic generation (shg) could be observed in pvnpak film without any poling procedure and 4.7 pm/v of effective second-order nonlinear optical susceptibility is obtained. the us particles as photosensitizers had a nanoscale size in pvnpak adopting transmission electron microscopy. the improvement of interface quality between us and polymer matrix is responsible for efficient photoinduced charge generation efficiency in the nanocomposites. an asymmetric optical energy exchange between two beams on the polymer composites pvnpak-cds/ecz has been found even without an external field in two-beam coupling (tbc) experiment, and the tbc gain and diffraction efficiency of 14.26 cm(-1) and 3.4% for pvnpak-5-cds/ecz, 16.43 cm(-1) and 4.4% for pvnpak-15-cds/ecz were measured at a 647.1 nm wavelength, respectively. |
| 收录类别 | EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000257335300047 |
| 公开日期 | 2009-09-18 |
| 源URL | [http://ir.siom.ac.cn/handle/181231/2278]  |
| 专题 | 上海光学精密机械研究所_信息光学开放实验室 |
| 推荐引用方式 GB/T 7714 | Ding Liyun,Jiang DeSheng,Huang Jun,et al. Photorefractive performance of a novel multifunctional inorganic-organic hybridized nanocomposite sensitized by CdS nanoparticles[J]. j. phys. chem. c,2008,112(27):10266, 10272. |
| APA | Ding Liyun.,Jiang DeSheng.,Huang Jun.,Erdan Gu.,刘立人.,...&刘德安.(2008).Photorefractive performance of a novel multifunctional inorganic-organic hybridized nanocomposite sensitized by CdS nanoparticles.j. phys. chem. c,112(27),10266. |
| MLA | Ding Liyun,et al."Photorefractive performance of a novel multifunctional inorganic-organic hybridized nanocomposite sensitized by CdS nanoparticles".j. phys. chem. c 112.27(2008):10266. |
入库方式： OAI收割
来源：上海光学精密机械研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。