Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films
文献类型:期刊论文
作者 | Zhang RG(张仁刚); Wang BY(王宝义)![]() ![]() ![]() ![]() |
刊名 | OPTICAL MATERIALS
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出版日期 | 2004 |
卷号 | 27期号:3页码:419-423 |
关键词 | ZnS sulfidation ZnO solar cells |
通讯作者 | Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Anal Tech, Beijing 100039, Peoples R China |
英文摘要 | Nanocrystalline ZnS films have been prepared by sulfidation of the reactive magnetron sputtered ZnO films. The structure, composition and optical properties of the sulfurized ZnO films as a function of the sulfidation temperature (Ts) have been systematically studied. It is found that at Ts greater than or equal to 400degreesC ZnO is completely converted to ZnS with the hexagonal structure. The ZnS films have a strongly (002) preferred orientation and an optical transparency of about 80% in the visible region. In addition, at Ts < 444.6degreesC (boiling point of sulfur), some residual sulfur decomposed from H2S gas can adhere to the sulfurized film surface while at Ts = 580degreesC a S/Zn ratio much higher than the ideal stoichiometric proportion of ZnS is obtained for the ZnS films. ZnS films with a minimum XRD FWHM value of 0.165degrees and a good S/Zn ratio of 0.99 are obtained at a temperature of 500degreesC indicating the ZnS films to be suitable for use in the thin film solar cells. (C) 2004 Elsevier B.V. All rights reserved. |
学科主题 | Materials Science; Optics |
类目[WOS] | Materials Science, Multidisciplinary ; Optics |
研究领域[WOS] | Materials Science ; Optics |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000225675500011 |
源URL | [http://ir.ihep.ac.cn/handle/311005/237402] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Zhang RG,Wang BY,Wan DY,et al. Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films[J]. OPTICAL MATERIALS,2004,27(3):419-423. |
APA | 张仁刚.,王宝义.,万冬云.,魏龙.,Zhang, RG.,...&Wei, L.(2004).Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films.OPTICAL MATERIALS,27(3),419-423. |
MLA | 张仁刚,et al."Effects of the sulfidation temperature on the structure, composition and optical properties of ZnS films prepared by sulfurizing ZnO films".OPTICAL MATERIALS 27.3(2004):419-423. |
入库方式: OAI收割
来源:高能物理研究所
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