Local structure of vanadium in doped LiFePO4
文献类型：期刊论文
| 作者 | Zhao T(赵挺); Xu W(徐伟) ; Ye Q(叶青); Cheng J(程杰); Zhao HF(赵海峰); Wu ZY(吴自玉); Chu WS(储旺盛); Zhao, T; Xu, W; Ye, Q
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| 刊名 | JOURNAL OF SYNCHROTRON RADIATION
 |
| 出版日期 | 2010 |
| 卷号 | 17期号:5页码:584-589 |
| 关键词 | lithium-ion battery LiFePO4 XAFS vanadium doping site |
| 通讯作者 | [Zhao, Ting ; Xu, Wei ; Ye, Qing ; Cheng, Jie ; Zhao, Haifeng ; Wu, Ziyu ; Chu, Wangsheng] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Wu, Ziyu] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230026, Peoples R China ; [Xia, Dingguo] Peking Univ, Coll Engn, Beijing 100871, Peoples R China |
| 英文摘要 | LiFePO4 composites with 5 at.% vanadium doping are prepared by solid state reactions. X-ray absorption fine-structure spectroscopy is used as a novel technique to identify vanadium sites Both experimental analyses and theoretical simulations show that vanadium does not enter into the LiFePO4 crystal lattice. When the vanadium concentration is lower then 1 at %, the dopant remains insoluble. Thus, a single-phase vanadium-doped LiFePO4 cannot be formed and the improved electrochemical properties of vanadium-doped LiFePO4 previously reported cannot be associated with crystal structure changes of the LiFePO4 via vanadium doping |
| 学科主题 | Instruments & Instrumentation; Optics; Physics |
| 类目[WOS] | Instruments & Instrumentation ; Optics ; Physics, Applied |
| 研究领域[WOS] | Instruments & Instrumentation ; Optics ; Physics |
| 原文出处 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000282083300002 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/238033]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_加速器中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhao T,Xu W,Ye Q,et al. Local structure of vanadium in doped LiFePO4[J]. JOURNAL OF SYNCHROTRON RADIATION,2010,17(5):584-589. |
| APA | 赵挺.,徐伟.,叶青.,程杰.,赵海峰.,...&Chu, WS.(2010).Local structure of vanadium in doped LiFePO4.JOURNAL OF SYNCHROTRON RADIATION,17(5),584-589. |
| MLA | 赵挺,et al."Local structure of vanadium in doped LiFePO4".JOURNAL OF SYNCHROTRON RADIATION 17.5(2010):584-589. |
入库方式： OAI收割
来源：高能物理研究所
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